85695-30-3Relevant academic research and scientific papers
Process for preparing (2,2,2-trihalo-1, 1-dihydrocarbyl-ethoxy) trihydrocarbylsilanes
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, (2008/06/13)
A process for forming trihalomethylsiloxanes by contacting a trihalosilane with a carbonyl in the presence of the fluoride ion. These compounds are used to form α-substituted acid chlorides.
TRICHLOROMETHYL ANION CHEMISTRY FROM TRIMETHYLSILYL TRICHLOROACETATE
Jesus, Miguel A. de,Prieto, J. Antonio,Valle, Luis del,Larson, Gerald L.
, p. 1047 - 1052 (2007/10/02)
The reaction of trimethylsilyl trichloroacetate with aldehydes and ketones in the presence of fluoride ion gives the trichloromethyl adducts.With potassium fluoride the reaction with cyclohexenone and crotonaldehyde results in clear 1,2 addition.
TRIMETHYLSILYL TRICHLOROACETATE: A NEW REAGENT FOR SALT-FREE SILYLATIONS
Renga, James M.,Pen-Chung, Wang
, p. 1175 - 1178 (2007/10/02)
Trimethylsylil trichloroacetate (1) is a convenient reagent for the silylation of phenols, carboxylic acids, mercaptans, amides, acetylenes, and β-keto esters, while the reaction of 1 with aldehydes and ketones affords silylated trichloromethyl carbinols (5).
