85706-52-1

Basic information

• Product Name: 3,9,10-TRIBROMO-(+)-CAMPHOR
• Synonyms: Bicyclo[2.2.1]heptan-2-one,3-bromo-1,7-bis(bromomethyl)-7-methyl-, [1S-(endo,anti)]-;(+)-3,9,10-Tribromocamphor; 3,9,10-Tribromocamphor
• CAS NO: 85706-52-1
• Molecular Formula: C10H13 Br3 O
• Molecular Weight: 0
• Mol File: 85706-52-1.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 380.7°C at 760 mmHg
• Flash Point: 111.5°C
• Appearance: /
• Density: 1.966g/cm³
• Vapor Pressure: 5.36E-06mmHg at 25°C
• Refractive Index: 1.599
• CAS DataBase Reference: 3,9,10-TRIBROMO-(+)-CAMPHOR(CAS DataBase Reference)
• NIST Chemistry Reference: 3,9,10-TRIBROMO-(+)-CAMPHOR(85706-52-1)
• EPA Substance Registry System: 3,9,10-TRIBROMO-(+)-CAMPHOR(85706-52-1)

Safety Data

• Hazardous Substances Data: 85706-52-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H13Br3O/c1-9(4-11)6-2-3-10(9,5-12)8(14)7(6)13/h6-7H,2-5H2,1H3

Upstream product

• 10293-10-4 3-endo-9-dibromo-1,7,7-trimethylbicyclo<2.2.1>heptan-2-one 
• 10293-06-8 (1R)-3-endo-bromocamphor 
• 1217497-39-6 (+)-endo-3,9-dibromocamphor 
• 464-49-3 (1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one 

Downstream Products

• 85706-53-2 (+)-endo-9,10-dibromocamphor 
• 98049-45-7 (1'R,2'R)-2-(2'-bromomethyl-2'-methyl-3'-methylenecyclopentyl)ethanoic acid 
• 85706-53-2 (1S)-9,10-dibromocamphor 
• 10293-09-1 (1R,4R,7R)-9-bromocamphor 
• 104672-33-5 (-)-anti-7,9-dibromofenchone 

Relevant articles and documents

An enantiospecific route to C,D ring synthons for steroid synthesis

A simple enantiospecific route to a hydrindenone intermediate for steroid synthesis has been accomplished.The introduction of a wide variety of side-chain units is made possible by stereoselective alkylation of a bicyclic ester 13 derived from (+)-camphor

Synthesis of 8,10-and 9,10-disubstituted camphor derivatives

Regiospecific bromination and debromination reactions have been used to provide a synthetic route from camphor to optically active 8,10- and 9,10-disubstituted camphor derivatives.