85726-77-8

Upstream product

• 85726-76-7 methyl 4-O-benzoyl-2,3-O-isopropylidene-α-D-rhamnopyranoside 
• 85726-75-6 Methyl-4-O-benzoyl-6-brom-6-desoxy-2,3-O-isopropyliden-α-D-mannopyranosid 
• 3492-44-2 α,α-dibromomethyl methyl ether 
• 98-88-4 benzoyl chloride 
• 3162-96-7 methyl-4,6-O-phenylmethylene-α-D-mannopyranoside 
• 85761-43-9 Methyl 4,6-O-benzylidene-2,3-O-isopropylidene-α-D-mannopyranoside 

Downstream Products

• 108365-30-6 Benzyl-O-(4-O-benzoyl-2-brom-2,6-didesoxy-3-O-formyl-β-D-glucopyranosyl)-(1->3)-O-(4-O-benzoyl-2-brom-2,6-didesoxy-β-D-glucopyranosyl)-(1->3)-4-O-benzoyl-2-brom-2,6-didesoxy-β-D-glucopyranosid 
• 113879-97-3 Benzyl-O-(4-O-benzoyl-2-brom-2,6-didesoxy-3-O-formyl-α-D-glucopyranosyl)-(1->3)-O-(4-O-benzoyl-2-brom-2,6-didesoxy-β-D-glucopyranosyl)-(1->3)-4-O-benzoyl-2-brom-2,6-didesoxy-β-D-glucopyranosid 
• 86448-03-5 C₃₄H₃₄Br₂O₁₀ 
• 86447-90-7 Benzoic acid (2R,3R,4S,5R,6R)-6-benzyloxy-5-bromo-4-formyloxy-2-methyl-tetrahydro-pyran-3-yl ester 
• 113921-70-3 Benzyl-O-(4-O-benzoyl-2,6-didesoxy-β-D-arabino-hexopyranosyl)-(1->3)-O-(4-O-benzoyl-2,6-didesoxy-β-D-arabino-hexopyranosyl)-(1->3)-4-O-benzoyl-2,6-didesoxy-β-D-arabino-hexopyranosid 
• 113879-98-4 Benzyl-O-(4-O-benzoyl-2-brom-2,6-didesoxy-β-D-glucopyranosyl)-(1->3)-O-(4-O-benzoyl-2-brom-2,6-didesoxy-β-D-glucopyranosyl)-(1->3)-4-O-benzoyl-2-brom-2,6-didesoxy-β-D-glucopyranosid 
• 108319-58-0 Benzyl-O-(4-O-benzoyl-2,6-didesoxy-β-D-erythro-hexopyranosid-3-ulose)-(1->3)-O-(4-O-benzoyl-2,6-didesoxy-β-D-arabino-hexopyranosyl)-(1->3)-4-O-benzoyl-2,6-didesoxy-β-D-arabino-hexopyranosid 
• 108319-65-9 benzyl 4-O-benzoyl-3-O-[4-O-benzoyl-3-O-(3-C-methylen-2,3,6-trideoxy-β-D-erythro-hexopyranosyl)-2,6-dideoxy-β-D-arabino-hexopyranosyl]-2,6-dideoxy-β-D-arabino-hexopyranoside 
• 108319-66-0 benzyl 4-O-benzoyl-3-O-[4-O-benzoyl-3-O-(3,3'-anhydro-2,6-dideoxy-3-C-hydroxymethyl-β-D-ribo-hexopyranosyl)-2,6-dideoxy-β-D-arabino-hexopyranosyl]-2,6-dideoxy-β-D-arabino-hexopyranoside 
• 108319-67-1 benzyl 3-O-[3-O-(2,6-dideoxy-3-C-methyl-β-D-ribo-hexopyranosyl)-2,6-dideoxy-β-D-arabino-hexopyranosyl]-2,6-dideoxy-β-D-arabino-hexopyranoside 
• 85726-82-5 Methyl-4-O-benzoyl-3-O-(4-O-benzoyl-2-brom-2,6-didesoxy-3-O-formyl-α-D-glucopyranosyl)-2-brom-2,6-didesoxy-β-D-glucopyranosid 
• 85726-81-4 Methyl-4-O-benzoyl-3-O-(4-O-benzoyl-2-brom-2,6-didesoxy-3-O-formyl-β-D-glucopyranosyl)-2-brom-2,6-didesoxy-β-D-glucopyranosid 
• 85726-84-7 Methyl-4-O-benzoyl-2,6-didesoxy-3-O-(3,4-di-O-acetyl-2,6-didesoxy-α-D-arabino-hexopyranosyl)-β-D-arabino-hexopyranosid 
• 85726-84-7 Methyl-4-O-benzoyl-2,6-didesoxy-3-O-(3,4-di-O-acetyl-2,6-didesoxy-β-D-arabino-hexopyranosyl)-β-D-arabino-hexopyranosid 

Relevant academic research and scientific papers

Formation of aureolic acid oligodeoxy mono-, di-, and trisaccharides employing the dibromomethyl methyl ether reaction

2,3-Isopropylidene D-rhamnopyranoside 2 obtained from mannose was treated with dibromomethyl methyl ether to give 2,6-dideoxy-2-bromo-glucopyranosyl bromide 5. Correspondingly, the D-talo precursor 3 led to the epimeric galacto-pyranosyl bromide 4. Both g

Synthesis of the Tetradeoxydisaccharide D-C of Aureolic Acids

Methyl 4-O-benzoyl-2,3-O-isopropylidene-α-D-rhamnopyranoside (3) is prepared in a straightforward way from methyl α-D-mannopyranoside, and reacts with dibromomethyl methyl ether to give the 2-bromo-2,6-dideoxy-α-D-glucopyranosyl bromide 7.Selective deform