85726-76-7Relevant academic research and scientific papers
Formation of aureolic acid oligodeoxy mono-, di-, and trisaccharides employing the dibromomethyl methyl ether reaction
Thiem, Joachim,Sch?ttmer, Bernhard
, p. 279 - 293 (2017/12/12)
2,3-Isopropylidene D-rhamnopyranoside 2 obtained from mannose was treated with dibromomethyl methyl ether to give 2,6-dideoxy-2-bromo-glucopyranosyl bromide 5. Correspondingly, the D-talo precursor 3 led to the epimeric galacto-pyranosyl bromide 4. Both g
GLYCOSAMINOGLYCAN (GAG) MIMETICS
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Page/Page column 18, (2010/02/12)
The invention relates to compounds that are designed to mimic the structure of GAGs; methods for the preparation of the compounds; compositions comprising the compounds; and use of the compounds and compositions thereof for the anti-angiogenic, anti-metas
Synthesis of a D-rhamnose branched tetrasaccharide, repeating unit of the O-chain from Pseudomonas syringae pv. Syringae (cerasi) 435
Bedini, Emiliano,Carabellese, Antonella,Corsaro, Maria Michela,De Castro, Cristina,Parrilli, Michelangelo
, p. 1907 - 1915 (2007/10/03)
The first synthesis of a D-rhamnose branched tetrasaccharide, corresponding to the repeating unit of the O-chain from Pseudomonas syringae pv. cerasi 435, as methyl glycoside is reported. The approach used is based on the synthesis of an opportune buildin
Deoxy and oxygen-substituted sugar-containing 14-aminosteroid compounds
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, (2008/06/13)
Disclosed are 14-aminosteroid compounds, including pharmaceutically acceptable acid salts and esters thereof, useful in treating individuals afflicted with congestive heart failure, which compounds have the general formula: STR1 wherein R3 is a
Convergent synthesis of an octasaccharide fragment of the O-specific polysaccharide of Shigella dysenteriae type 1
Pozsgay, Vince,Pannell, Lewis
, p. 105 - 122 (2007/10/02)
A stereocontrolled, convergent synthesis is described of the linear octasaccharide methyl glycoside α-L-Rhap-(1 -> 2)-α-D-Galp-(1 -> 3)-α-GlcpNAc-(1 -> 3)-α-L-Rhap-(1 -> 3)-α-L-Rhap-(1 -> 2)-α-D-Galp-(1 -> 3)-α-D-GlcpNAc-(1 -> 3)-α-L-Rhap-OMe (11), which
SYNTHESIS OF A COMMON POLYSACCHARIDE ANTIGEN OF PSEUDOMONAS AERUGINOSA AS THE 6-AMINOHEXYL GLYCOSIDE
Tsvetkov, Yury E.,Backinowsky, Leon V.,Kochetkov, Nikolay K.
, p. 75 - 90 (2007/10/02)
The synthesis is described of a tritylated 1,2-O-cyanoethylidene derivative (3) of the trisaccharide α-D-Rha-(1->2)-α-D-Rha-(1->3)-D-Rha.Triphenylmethylium perchlorate-catalysed polycondensation of 3 in the presence of 6-phthalimidohexyl 2,4-di-O-benzoyl-3-O-trityl-α-D-rhamnopyranoside followed by deprotection afforded the 6-aminohexyl glycoside of a D-rhamnan corresponding to a common polysaccharide antigen of Pseudomonas aeruginosa.
SYNTHESIS OF THE O-SPECIFIC POLYSACCHARIDE OF SHIGELLA FLEXNERI
Kotchekov, N. K.,Byramova, N. E.,Tsvetkov, Yu. E.,Backinowsky, L. V.
, p. 3363 - 3375 (2007/10/02)
A regular heteropolysaccharide built of tetrasaccharide repeating units is synthesised by means of regio- and stereospecific polycondensation of tritylated cyanoethylidene derivative.The polysaccharide obtained is identical with the O-antigenic polysaccharides of Shigella flexneri serotypes 3b, 3c, and variant Y.It also represents the basic chain of O-antigenic polysaccharides of all serotypes of this bacterium.
Synthesis of the Tetradeoxydisaccharide D-C of Aureolic Acids
Thiem, Joachim,Gerken, Manfred,Bock, Klaus
, p. 462 - 470 (2007/10/02)
Methyl 4-O-benzoyl-2,3-O-isopropylidene-α-D-rhamnopyranoside (3) is prepared in a straightforward way from methyl α-D-mannopyranoside, and reacts with dibromomethyl methyl ether to give the 2-bromo-2,6-dideoxy-α-D-glucopyranosyl bromide 7.Selective deform
