857463-55-9

Upstream product

• 857463-64-0 C₂₇H₄₀O₂ 
• 144072-79-7 (2E,6E,10E)-1-(benzyloxy)-3,7,11,15-tetramethyl-2,6,10,14-hexadecatetraene 

Downstream Products

• 857463-56-0 ethyl (E,E,E,E)-16-benzyloxy-2,6,10,14-tetramethyl-2,6,10,14-hexadecatetraenoate 
• 857463-58-2 (E,E,E,E)-[16,16,16-2H₃]-1-benzyloxy-3,7,11,15-tetramethyl-2,6,10,14-hexadecatetraene 
• 857463-57-1 (E,E,E,E)-[1-2H₂]-16-benzyloxy-2,6,10,14-tetramethyl-2,6,10,14-hexadecatetraen-1-ol 
• 910247-06-2 C₂₄H₃₆O₂ 

Relevant academic research and scientific papers

Enantioselective synthesis of α-terpineol and nephthenol by intramolecular acyloxazolidinone enolate alkylations

Enolate anions generated from norterpenyl bromides bearing oxazolidinone chiral auxiliaries at the chain termini underwent efficient, stereo-biased cyclizations to form 6- and 14-membered rings in novel synthetic routes to α-terpineol and nephthenol enantiomers. The Royal Society of Chemistry 2006.

Stereochemistry of the macrocyclization and elimination steps in taxadiene biosynthesis through deuterium labeling

Taxadiene synthase catalyzes the cyclization of (E,E,E)-geranylgeranyl diphosphate (GGPP) to taxa-4(5),11(12)-diene (Scheme 1, 5 → 2) as the first committed step of Taxol biosynthesis. Deuterated GGPPs labeled stereospecifically at C-1, C-4, and C-16 were