144072-79-7Relevant academic research and scientific papers
Regio- and Stereoselective Synthesis of 1,5-Dienes Using Allylic Barium Reagents
Yanagisawa, Akira,Hibino, Hiroaki,Habaue, Shigeki,Hisada, Yoshiyuki,Yasue, Katsutaka,Yamamoto, Hisashi
, p. 1263 - 1268 (1995)
The highly α,α' selective and sterocontrolled homocoupling reaction of allylic halides was achieved using barium reagent.The double-bond geometry of the starting allylic chloride was completely retained.The α,α' cross-coupling products were also prepared stereospecifically and regioselectively by this method.
Highly Selective Homocoupling Reaction of Allylic Halides Using Barium Metal
Yanagisawa, Akira,Hibino, Hiroaki,Habaue, Shigeki,Hisada, Yoshiyuki,Yamamoto, Hisashi
, p. 6386 - 6387 (2007/10/02)
The highly α,α' selective and stereocontrolled homocoupling reaction of allylic halides was achieved using barium reagent.The double-bond geometry of the starting allylic chloride was completely retained. α,α' Cross-coupling products were also prepared stereospecifically and regioselectively by this method.
Two-functional-group-containing terpenoids
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, (2008/06/13)
A process for the preparation of a two-functional-group-containing terpen having the general formula: STR1 in which n is an integer of from 1 to 5, R represents a hydroxymethyl, formyl, or carboxyl group, and A represents the hydrogen atom, or a 2-tetrahydropyranyl, benzyl, methoxymethol or methoxyethoxymethyl group comprising the oxidation with a microorganism belonging to the genus Nocardia. Some of the terpenoids are of value as anti-ulcer agents, while others are useful as intermediates.
