85761-38-2

Basic information

• Product Name: Cyclohexanol, 2-(phenylmethoxy)-, (1R,2R)-
• CAS NO: 85761-38-2
• Molecular Formula: C13H18O2
• Molecular Weight: 206.285
• Mol File: 85761-38-2.mol
• Article Data: 26

Chemical Properties

• CAS DataBase Reference: Cyclohexanol, 2-(phenylmethoxy)-, (1R,2R)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanol, 2-(phenylmethoxy)-, (1R,2R)-(85761-38-2)
• EPA Substance Registry System: Cyclohexanol, 2-(phenylmethoxy)-, (1R,2R)-(85761-38-2)

Safety Data

• Hazardous Substances Data: 85761-38-2(Hazardous Substances Data)

Upstream product

• 286-20-4 cyclohexane-1,2-epoxide 
• 100-51-6 benzyl alcohol 
• 1792-81-0 cis-1,2-cyclohexane 
• 100-44-7 benzyl chloride 
• 100-39-0 benzyl bromide 
• 822-67-3 Cyclohex-2-enol 
• 32700-48-4 [(cyclohex-2-en-1-yloxy)methyl]benzene 
• 1192-78-5 2,3-epoxycyclohexanol 
• 84029-20-9 racemic cis-1-benzyloxy-7-oxabicyclo[4.1.0]heptane 
• 1460-57-7 trans-1,2-cyclohexandiol 
• 84029-20-9 (±)-(1R,2S,6S)-2-(benzyloxy)-7-oxabicyclo[4,1,0]heptane 
• 286-20-4 cyclohexene oxide 
• 29494-42-6 1-(benzyloxy)cyclohexene 
• 110-82-7 cyclohexane 

Downstream Products

• 125992-58-7 (1S,2R)-2-(benzyloxy)cyclohexan-1-ol 
• 125992-59-8 Acetic acid (1R,2S)-2-benzyloxy-cyclohexyl ester 
• 64714-16-5 2-phenyl-4,5-trans-tetrametylene-1,3-dioxolan 
• 880498-21-5 (2R)-2-benzyloxycyclohexanone 
• 1072-86-2 (1R,2R)-trans-1,2-cyclohexanediol 
• 57794-08-8 (1S,2S)-trans-1,2-Cyclohexanediol 
• 98454-42-3 (±)-trans-2-(benzyloxy)cyclohexanamine 
• 931-16-8 (+/-)-trans-2-aminocyclohexanol 
• 121282-70-0 (+/-)-trans-1-hydroxy-2-tert-butoxycarbonylamino-cyclohexane 

Relevant articles and documents

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Benzoxaborole Catalyst for Site-Selective Modification of Polyols

The site-selective modification of polyols bearing several hydroxyl groups without the use of protecting groups remains a significant challenge in synthetic chemistry. To address this problem, novel benzoxaborole derivatives were designed as efficient catalysts for the highly site-selective and protecting-group-free modification of polyols. To identify the effective substituent groups enhancing the catalytic activity and selectivity, a series of benzoxaborole catalysts 1a–k were synthesized. In-depth analysis for the substituent effect revealed that 1i–k, bearing multiple electron-withdrawing fluoro- and trifluoromethyl groups, exhibited the greatest catalytic activity and selectivity. Moreover, 1i-catalyzed benzoylation, tosylation, benzylation, and glycosylation of various cis-1,2-diol derivatives proceeded with good yield and site-selective manner.

Lanthanide-based coordination polymers as promising heterogeneous catalysts for ring-opening reactions

This work presents the synthesis and structural characterization of Eu3+- and Tb3+-based coordination polymers starting from a Co3+-based metalloligand offering appended arylcarboxylic acid groups. Both coordination polymers function as reusable heterogeneous catalysts for ring-opening reactions utilizing amines, alcohols, thiols, and azides as the nucleophiles. The catalytic results illustrate an excellent control over the regioselectivity whereas a filtration test and mechanistic studies substantiate Lewis-acid catalyzed activation of the epoxide during the reaction.