85773-83-7Relevant academic research and scientific papers
STEREOCHEMISTRY IN THE PALLADIUM-CATALYZED REARRANGEMENT OF SOME CYCLOHEX-2-ENYL ACETOACETATES
Fiaud, J. C.,Aribi-Zouioueche, L.
, p. 5279 - 5282 (1982)
The palladium-catalyzed decarboxylation and rearrangement of cis-5-substituted-cyclohex-2-enyl acetoacetates to give the corresponding methyl ketone proceed mostly with retention of configuration, indicative of an enolate addition to the ?-allylic ligand trans to the palladium.The reaction from the trans-isomer is not stereoselective.
