Tetrahedron Letters p. 5279 - 5282 (1982)
Update date:2022-08-05
Topics:
Fiaud, J. C.
Aribi-Zouioueche, L.
The palladium-catalyzed decarboxylation and rearrangement of cis-5-substituted-cyclohex-2-enyl acetoacetates to give the corresponding methyl ketone proceed mostly with retention of configuration, indicative of an enolate addition to the ?-allylic ligand trans to the palladium.The reaction from the trans-isomer is not stereoselective.
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(2011)
