85785-71-3

Upstream product

• 89162-97-0 (R)-(+)-3,4-dimethyl-2-cyclohexen-1-one 
• 75337-05-2 (+)-(R)-4-methyl-2-cyclohexene-1-one 
• 85785-69-9 (3R,4R,5R)-3,4,5-Trimethyl-4-[(1E,3E)-3-methyl-5-(tetrahydro-pyran-2-yloxy)-penta-1,3-dienyl]-2-oxo-cyclohexanecarbaldehyde 
• 85785-68-8 (4R,5R)-4,5-Dimethyl-4-[(1E,3E)-3-methyl-5-(tetrahydro-pyran-2-yloxy)-penta-1,3-dienyl]-2-oxo-cyclohexanecarbaldehyde 
• 10463-42-0 3,4-dimethyl-cyclohex-2-enone 
• 41967-81-1 (E)-tetrahydro-2-<(3-methyl-2-penten-4-ynyl)oxy>-2H-pyran 
• 6153-06-6 3-methylpent-2-en-4-yn-1-ol 
• 85785-70-2 (2S,3S,4S)-2,3,4-Trimethyl-3-[(1E,3E)-3-methyl-5-(tetrahydro-pyran-2-yloxy)-penta-1,3-dienyl]-cyclohexanone 

Downstream Products

• 85785-72-4 (2EZ,4E,1'R,2'R,6'R)-(-)-5-(1',2',6'-trimethyl-3'-oxocyclohexyl)-3-methyl-2,4-pentadienyl acetate 
• 99529-53-0 3-Chloro-4,6-dihydroxy-2-methyl-5-[(2E,4E)-3-methyl-5-((6R,7R,8R)-6,7,8-trimethyl-1,4-dioxa-spiro[4.5]dec-7-yl)-penta-2,4-dienyl]-benzaldehyde 
• 85785-76-8 (2'E,4'E,1''R,2''R,6''R)-3-<5'-(3'',3''-ethylenedioxy-1'',2'',6''-trimethylcyclohexyl)-3'-methyl-2',4'-pentadienyl>-1,5-dichloro-6-methyl-2,4-cyclohexanedione 
• 99529-52-9 (2'E,4'E,1''R,2''R,6''R)-4-chloro-2-<5'-(3'',3''-ethylenedioxy-1'',2'',6''-trimethylcyclohexyl)-3'-methyl-2',4'-pentadienyl>orcinol 
• 85912-78-3 (2'E,4'E,1''R,2''R,6''R)-3-<5'-(3'',3''-ethylenedioxy-1'',2'',6''-trimethylcyclohexyl)-3'-methyl-2',4'-pentadienyl>-2,4-dimethoxy-6-methyl-1,4-cyclohexadiene 
• 26166-39-2 Ascochlorin 
• 91854-87-4 3-chloro-4,6-dihydroxy-2-methyl-5-decane)-2,4-pentadienyl>benzaldehyde 
• 91854-87-4 3-Chloro-4,6-dihydroxy-2-methyl-5-[(2Z,4E)-3-methyl-5-((6R,7R,8R)-6,7,8-trimethyl-1,4-dioxa-spiro[4.5]dec-7-yl)-penta-2,4-dienyl]-benzaldehyde 
• 85785-76-8 (+/-)-(2'Z,4'E)-<5'-(3,3-ethylenedioxy-1,2,6-trimethylcyclohexyl)-3'-methyl-2',4'-pentadienyl>-1,5-dichloro-6-methyl-2,4-cyclohexanedione 
• 91854-86-3 (+/-)-(2'Z,4'E)-4-chloro-2-<5'-(3,3-ethylenedioxy-1,2,6-trimethylcyclohexyl)-3'-methyl-2',4'-pentadienyl>orcinol 
• 85912-78-3 (+/-)-(2'Z,4'E)-3-<5'-(3,3-ethylenedioxy-1,2,6-trimethylcyclohexyl)-3'-methyl-2',4'-pentadienyl>-2,4-dimethoxy-6-methyl-1,4-cyclohexadiene 
• 26166-39-2 (+/-) ascochlorin 
• 26166-39-2 3-Chloro-4,6-dihydroxy-2-methyl-5-[(2Z,4E)-3-methyl-5-((1S,2S,6S)-1,2,6-trimethyl-3-oxo-cyclohexyl)-penta-2,4-dienyl]-benzaldehyde 
• 85785-76-8 (+/-)-(2'E,4'E)-3-<5'-(3,3-ethylenedioxy-1,2,6-trimethylcyclohexyl)-3'-methyl-2',4'-pentadienyl>-1,5-dichloro-6-methyl-2,4-cyclohexanedione 

Relevant academic research and scientific papers

SYNTHESIS OF THE NATURAL ENANTIOMERS OF ASCOCHLORIN, ASCOFURANONE AND ASCOFURANOL

Three fungal metabolites with a common structural feature as prenylated phenols were synthesized in their naturally occuring and optically active forms: ascochlorin benzaldehyde>, ascofuranone and ascofuranol benzaldehyde>. (+)-Ascofuranone and (+)-ascofuranol were also synthesized.By the present synthesis the absolute configuration of the natural (-)-ascofuranol was established as (1''S,4''S).

SYNTHESIS OF (+/-)-ASCOCHLORIN, (+/-)-ASCOFURANONE AND LL-Z1272α

Three antibiotics with a common structural feature as prenylated phenols were synthesized: (+/-)-ascochlorin (5-chloro-2,4-dihydroxy-6-methyl-3-benzaldehyde), (+/-)-ascofurano