858932-57-7

Upstream product

• 108-05-4 vinyl acetate 
• 858932-54-4 (E)-5-methyl-4-phenyl-3-hexen-2-ol 
• 876953-21-8 (E)-5-methyl-4-phenyl-3-hexen-2-one 
• 62751-30-8 (E)-ethyl 4-methyl-3-phenylpent-2-enoate 
• 914400-07-0 (E)-N-methoxy-N,4-dimethyl-3-phenylpent-2-enamide 
• 611-70-1 phenyl isopropyl ketone 

Downstream Products

• 858932-76-0 (2S,4R)-4-hydroxy-2-isopropyl-2-phenylpentanenitrile 
• 858932-74-8 (2S,4S)-4-hydroxy-2-isopropyl-2-phenylpentanenitrile 
• 858932-60-2 (E,R)-3-isopropyl-3-phenyl-4-hexenoic acid 
• 858932-67-9 (1R,3S)-acetic acid 3-formyl-1,4-dimethyl-3-phenylpentyl ester 
• 858932-68-0 (1S,3S)-acetic acid 3-formyl-1,4-dimethyl-3-phenylpentyl ester 

Relevant academic research and scientific papers

The synthesis of non-racemic β-alkyl-β-aryl-disubstituted allyl alcohols and their transformation into allylamines and amino acids bearing a quaternary stereocenter

A synthesis of non-racemic β-alkyl-β-aryl allyl alcohols and their transformation into allylamines bearing a quaternary stereogenic center is reported. The allyl alcohols were prepared either by Cu-catalyzed enantioselective reduction of enones or by sequ

Synthesis of isoaminile mediated by enzymes

A lipase-mediated synthesis of all four enantiomers of isoaminile is reported. The key issues of the paper are: (i) enantioselective acetylation of allylic alcohol (E)-(±)-5 to give (E,S)-5 (ee = 92%) and (E,R)-6 (ee > 99%); (ii) Claisen-Johnson rearrange