85969-43-3

Basic information

• Product Name: N-acetyl-2-(m-chlorobenzoyloxy)-3,4-dihydro-3-hydroxy-2,3-diphenyl-2H-1,4-benzoxazine
• Synonyms: N-acetyl-2-(m-chlorobenzoyloxy)-3,4-dihydro-3-hydroxy-2,3-diphenyl-2H-1,4-benzoxazine
• CAS NO: 85969-43-3
• Molecular Weight: 499.95
• Mol File: 85969-43-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-acetyl-2-(m-chlorobenzoyloxy)-3,4-dihydro-3-hydroxy-2,3-diphenyl-2H-1,4-benzoxazine(CAS DataBase Reference)
• NIST Chemistry Reference: N-acetyl-2-(m-chlorobenzoyloxy)-3,4-dihydro-3-hydroxy-2,3-diphenyl-2H-1,4-benzoxazine(85969-43-3)
• EPA Substance Registry System: N-acetyl-2-(m-chlorobenzoyloxy)-3,4-dihydro-3-hydroxy-2,3-diphenyl-2H-1,4-benzoxazine(85969-43-3)

Safety Data

• Hazardous Substances Data: 85969-43-3(Hazardous Substances Data)

Upstream product

• 1239-56-1 1-(2,3-diphenyl-1H-indol-1-yl)ethan-1-one 
• 937-14-4 3-chloro-benzenecarboperoxoic acid 

Downstream Products

• 78154-49-1 o-phenol 
• 95-55-6 2-amino-phenol 
• 134-81-6 benzil 
• 535-80-8 3-chlorobenzoate 

Relevant articles and documents

Oxidation of 2,3-Disubstituted Indoles with m-Chloroperbenzoic Acid. Formation of o-Aminophenol Derivatives and a Dimeric Product

Oxidation of tetrahydrocarbazole (5) with m-chloroperbenzoic acid in methylene dichloride at -60 deg C gave the N-benzoyl-o-aminophenol (11) togehter with the hydroxy-3H-indole (7) and the indol-3(2H)-one (9).The N-benzoyl-o-aminophenol (11) was found to be derived from the hydroxy-4aH-carbazole (7) via an unstable tertiary amine intermediate (17) by further oxidation.The N-benzoyl-o-aminophenol (11) was also obtained by the oxidation of the other hydroxy-3H-indoles (18), (19), and (24).On the other hand, similar oxidation of N-methyl-tetrahydrocarbazole (6) gave the hydroxyenamine (28) and its dimer (27), and of 2,3-diphenylindole (31) and the N-methyl derivative (30) gave the hydroxy-3H-indole (19) and the ketoamide (33), while the 1,4-benzoxazine derivatives (34) and (35) were obtained in the case of the N-acetyl derivative (32).