85976-52-9Relevant academic research and scientific papers
FREE RADICALS. XXII. REACTIONS OF "ELECTRON-DEFICIENT" RADICALS WITH ORGANOMAGNESIUM AND ORGANOMERCURY COMPOUNDS
Tanaseichuk, B. S.,Belozerov, A. I.,Sanaeva, E. P.,Butin, K. P.
, p. 494 - 497 (2007/10/02)
The reactions of triphenylimidazolyl and diphenylaminyl radicals with methylmagnesium iodide, phenylmagnesium bromide, and dibenzylmercury were studied.It was shown that the radicals are reduced to anions and the radicals in the organometallic compounds are displaced.The homolytic nature of the displacement of the radical from the organometallic compounds ( SH2 reaction ) is confirmed by its capture by 2,4,6-tribromonitrosobenzene with formation of a nitroxyl radical.
