85982-88-3Relevant articles and documents
Stereoselective trimethylsilylation of α- and β-galactopyranoses
Asami, Yuri,Kawaguchi, Yuka,Kanie, Yoshimi,Abdu-Allah, Hajjaj,Suzuki, Katsuhiko,Kanie, Osamu
, p. 51 - 56 (2019/02/07)
Trimethylsilylation of the anomeric hydroxyl groups of tetra-O-benzyl and tetra-O-acetyl galactopyranoses was investigated. Stereoselective formation of β-trimethylsilyl glycoside (β-TMS glycoside) of benzyl protected compound was achieved using N-trimeth
Studies on Glycosides VII. A Highly Stereoselective Synthesis of 1-Thioglycosides
Li, Zhan-Jiang,Liu, Ping-Li,Li, Zhong-Jun,Qiu, Dong-Xu,Cai, Meng-Shen
, p. 2169 - 2175 (2007/10/02)
A facile method for the synthesis of 1-thioglycosides using 1-α-O-trimethylsilyl-2,3,4,6,-tetra-O-benzyl-D-gluco- or manno-pyranoside by the promotion of BF3Et2O was reported.The reaction conditions were very mild, and 1-thioglycosides were obtained in hi