85995-48-8

Basic information

• Product Name: N-Nitroso-N-benzylformamide-d₁
• Synonyms: N-Nitroso-N-benzylformamide-d₁
• CAS NO: 85995-48-8
• Molecular Weight: 165.156
• Mol File: 85995-48-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-Nitroso-N-benzylformamide-d₁(CAS DataBase Reference)
• NIST Chemistry Reference: N-Nitroso-N-benzylformamide-d₁(85995-48-8)
• EPA Substance Registry System: N-Nitroso-N-benzylformamide-d₁(85995-48-8)

Safety Data

• Hazardous Substances Data: 85995-48-8(Hazardous Substances Data)

Upstream product

• 85995-47-7 N-benzyl(²_H)formamide 
• 100-46-9 benzylamine 
• 88333-03-3 Benzyl isocyanide 

Downstream Products

• 91-20-3 naphthalene 
• 100-39-0 benzyl bromide 

Relevant articles and documents

Reaction of N-Nitroso-N-benzylformamide with Phenylmagnesium Bromide and Phenyllithium

The action of aryl Grignard and lithium reagents on N-nitroso-N-benzylformamide (1) leads to products whose formation can be understood in terms of the intermediacy of benzyldiazotate ion.However, the presence of "hydrogen abstraction" products, e. g., anisole or naphthalene, coupled with the near absence of products traceable to the aldehyde moiety (expected from the attack at the formyl group) with 1 equiv of organometallics, suggests the initial formation of a complex.Possible rationalizations for the formation of the products are presented.