860623-40-1Relevant articles and documents
Preparation and crystal structures of a series of titanium(III) 9-BBN hydroborate complexes containing Ti...H agostic interactions
Ding, Errun,Du, Bin,Liu, Fu-Chen,Liu, Shengming,Meyers, Edward A.,Shore, Sheldon G.
, p. 4871 - 4878 (2005)
9-BBN hydroborate complexes Ti{(μ-H)2BC8H 14}3(THF)2 (1), Ti{(μ-H)2BC 8H14}3(OEt2) (2), and [K(OEt 2)4]-[Ti{(μ-H)2BC8H 14}4] (4) were formed from the reaction of TiCl 4 with K[H2BC8H14] in diethyl ether or THF. Ti{(μ-H)2BC8H14} 3(PhNH2) (3) was isolated from the reaction of 2 with aniline in diethyl ether. In the formation of these complexes, Ti(IV) is reduced to Ti(III). The coordinated diethyl ether in 2 can be displaced by the stronger bases THF and aniline, to form 1 and 3, respectively. All of the compounds were characterized by single-crystal X-ray diffraction analysis. In complex 1, which contains two coordinated THF ligands, the titanium possesses a 17 electron configuration and there is no evidence for agostic interaction. Complexes 2 and 3 contain only one coordinated ether or aniline ligand, and the titanium possesses a 15 electron configuration. In these compounds, a C-H hydrogen on an α carbon on the BC8H14 unit of a 9-BBN hydroborate ligand forms an agostic interaction with the titanium. Criteria for assessing the existence of agostic interactions are discussed. As the potassium salt, the anion of complex 4 is more stable than the complexes 1-3. Organometallic anions of the type [ML4]- for titanium(III) are rare.
