860792-53-6

Upstream product

• 850704-74-4 dimethyl 3-(1-formylpropyl)glutarate 
• 80582-39-4 (2S)-2-amino-3-(3,4-dimethoxyphenyl)-1-propanol 
• 759-31-9 diethyl 2-(1-ethyl-3-methyl-2-butenyl)malonate 
• 17085-88-0 diethyl propylidenemalonate 
• 860792-46-7 2-(1-ethyl-3-methyl-2-butenyl)-1,3-propanediol ditosylate 
• 860792-47-8 3-(1-ethyl-3-methyl-2-butenyl)pentanedinitrile 
• 860792-45-6 2-(1-ethyl-3-methyl-2-butenyl)-1,3-propanediol 
• 860792-49-0 dimethyl 3-(1-ethyl-3-methyl-2-butenyl)pentanedioate 
• 860792-48-9 3-(1-ethyl-3-methyl-2-butenyl)pentanedioic acid 

Relevant academic research and scientific papers

Straightforward methodology for the enantioselective synthesis of benzo[a]- and indolo[2,3-a]quinolizidines

(Chemical Equation Presented) An enantioselective two-step route to substituted benzo[a]- and indolo[2,3-a]quinolizidines has been developed. It consists of (i) a stereoselective cyclocondensation of a racemic or prochiral δ-oxo(di)ester with either (S)-(

Biogenetically inspired enantioselective approach to indolo[2,3-a]- and benzo[a]quinolizidine alkaloids from a synthetic equivalent of secologanin

(Chemical Equation Presented) Racemic oxodiester 1 undergoes stereoselective cyclocondensation with (S)-tryptophanol, (S)-(3,4- dimethoxyphenyl)alaninol, or the corresponding amino acids, in a process involving a tandem dynamic kinetic resolution/desymmetrization of diastereotopic groups, to give bicyclic lactams, which are cyclized to substituted indolo[2,3-a]- and benzo[a]quinolizidines.