861025-12-9Relevant academic research and scientific papers
Rhodium(III)-catalyzed azidation and nitration of arenes by C-H activation
Xie, Fang,Qi, Zisong,Li, Xingwei
supporting information, p. 11862 - 11866 (2013/11/19)
Getting a handle on it: In the chelation-assisted title reactions in the presence of a hypervalent iodine oxidant, sodium azide and sodium nitrite served as readily available nitrogen sources, and pyridine, pyrimidine, and pyrazole substituents were effic
Copper-mediated chelation-assisted ortho nitration of (hetero)arenes
Zhang, Lin,Liu, Zhenhua,Li, Huiqin,Fang, Guichun,Barry, Badru-Deen,Belay, Tuemay Abadi,Bi, Xihe,Liu, Qun
supporting information; experimental part, p. 6536 - 6539 (2012/02/04)
A novel copper-mediated chelation-assisted ortho C-H nitration of (hetero)arenes has been developed for the first time, which used dioxygen as terminal oxidant and 1, 2, 3-TCP as solvent, leading to the synthesis of nitroaromatics with excellent regiosele
