86108-56-7

Usage

Chemical composition

1-Methyl-2-trimethylstannylimidazole consists of a methyl group and a trimethylstannyl group attached to an imidazole ring.

Usage in organic synthesis

It is commonly used as a building block for creating more complex compounds.

Reactive site

The trimethylstannyl group serves as a reactive site for further chemical reactions.

Diverse functionalization

The imidazole ring provides opportunities for diverse functionalization.

Pharmaceutical industry application

It is often utilized for creating new drug candidates.

Materials science application

It is used for designing novel materials with specific properties.

Handling precautions

It is important to handle this chemical with care due to the toxic nature of the trimethylstannyl group and its potential environmental impact.

Upstream product

• 616-47-7 1-methyl-1H-imidazole 
• 1066-45-1 trimethyltin(IV)chloride 

Downstream Products

• 616-47-7 1-methyl-1H-imidazole 
• 56-24-6 trimethyltin(IV) hydroxide 
• 66787-69-7 2-Fluor-1-methylimidazol 

Relevant academic research and scientific papers

Trimethylstannyl- and Dimethylstannyl-substituted Pyrroles-Synthesis, Spectra, and Structures

Monomeric trimethylstannyl pyrroles, Me3SnR (Me=CH3 and R=-NC4H4, -NC4H2Me2-2,5, -NC4Me4-2,3,4,5, -C4H3NMe-1), are synthesized by metathesis reactions from Me3SnCl with 1(N)- and 2(C)-lithiumpyrroles, respectively. An almost similar procedure gives monomeric dimethylstannylbis(pyrroles),Me2SnR2 (1a-3a), from Me2SnCl2 and 1-Li-pyrrolides (1:2 molar ratio) in good yields. Lithiated 1,2,5-trimethylpyrrole and Me3SnCl forms the com pound Me3Sn-CH2-C4H2Me(-5)NMe (8), the reaction of Me2SnCl2 with 2-lithium-1-methylpyrrole gives oligomeric [Me2Sn-C4H2NMe-]x, (6a). The mass-, NMR, and vibrational spectra have been measured and discussed. The results of the X-ray structure determinations of Me3Sn-NC4H4 (1) and Me2Sn(-NC4Me4)2 (3a) are compared with the structure of the known dimethylmetal pyrroles of Al, Ga, and In.

Organotin Biocides. XIII. C-Triorganostannylimidazoles, -benzoxazoles and -benzothiazoles

The synthesis, spectroscopic characterisation, and reactivity of a series of triorganotin imidazoles, benzothiazoles and benzoxazoles R3Sn(Het) (R=Me, Bu, Ph) are described.The structure of 2-(triphenylstannyl)benzothiazole has been determined by crystallographic methods.Space group: Triclinic, P1; a 9.501(1), b 10.172(2), c 13.231(2) Angstroem, β 70.46(1), γ 69.71(1) deg, U 1082.8 Angstroem3, F(000)=484, μ(Mo-Kα) 11.74 cm-1, R=0.0719 for 2264 reflections with I>3?I.The geometry at the tin is tetrahedral.Bond angles at tin are used to discuss the reactivity and Moessbauer spectra of these species.

ZUR SYNTHESE EINIGER NEUER HETEROCYCLISCH SUBSTITUIERTER STANNANE

The in 2-position trimethylstannylated heterocycles are formed in good yields by reaction of the lithiated heterocycles benzothiazole, N-methylbenzimidazole, N-methylimidazole, N-methyltriazole, pyridine, chinoline and thiazole with trimethylchlorostannane.The thermolabile lithium compounds are synthesized by metallation or by metal-halogen exchange reactions according to known procedures.