861395-19-9

Upstream product

• 5724-03-8 1-(4-fluorophenyl)allyl alcohol 
• 108-24-7 acetic anhydride 
• 459-57-4 4-fluorobenzaldehyde 

Downstream Products

• 205108-06-1 (E)-3-(4'-fluorophenyl)-2-propen-1-ol acetate 
• 1562996-56-8 (S)-1-(4-fluorophenyl)-N-(2-methoxyethyl)-N-methylprop-2-en-1-amine 
• 1562996-36-4 (S)-1-(1-(4-fluorophenyl)allyl)-4-phenylpiperazine 
• 1562996-35-3 (S)-1-(1-(4-fluorophenyl)allyl)-4-phenylpiperidine 
• 1562996-34-2 (S)-4-(1-(4-fluorophenyl)allyl)morpholine 

Relevant academic research and scientific papers

Kinetic resolution of allylic alcohols via stereoselective acylation catalyzed by lipase PS-30

By using lipase PS-30 as catalyst, the kinetic resolution of a series of racemic allylic alcohols has been achieved via stereoselective acylation. The value of kinetic enantiomeric ratio (E) reached up to 968. Substituent effect is briefly discussed.

[(NHC)Au1]-catalyzed rearrangement of allylic acetates

Equation Presented [(NHC)AuCl] complexes (NHC = N-heterocyclic carbene), in conjunction with a silver salt, were found to efficiently catalyze the rearrangement of allylic acetates under both conventional and microwave-assisted heating. The optimization of several reaction parameters (solvent, silver salt, and ligand) as well as a study of the reaction scope are reported. The steric hindrance of the ligand bound to gold was found crucial for the outcome of the reaction as only extremely bulky ligands permitted the isomerization.