205108-06-1Relevant articles and documents
Ruthenium-Catalyzed Cross-Metathesis of Allyl Acetate and Styrenes: A Practical Approach to the Synthesis of Tripolinolate A and Its Analogs
Araki, Yasuhiro,Topolov?an, Nikola,Kotora, Martin
, p. 1736 - 1739 (2017)
The scope of the Ru-catalyzed cross-metathesis of allyl acetates and styrenes was explored. A variety of electronically and structurally divergent styrenes were tolerated, and the resultant products were obtained in reasonable yields. The reported method was utilized in the synthesis of inhibitors of the proliferation of glioma and colorectal cancer cells, tripolinolate A and its diacetate analog.
Selenium-catalyzed C(sp3)-H acyloxylation: Application in the expedient synthesis of isobenzofuranones
Kr?tzschmar, Felix,Kassel, Martin,Delony, Daniel,Breder, Alexander
, p. 7030 - 7034 (2015/05/05)
Oxidative Se-catalyzed C(sp3)-H bond acyloxylation has been used to construct a diverse array of isobenzofuranones from simple ortho-allyl benzoic acid derivatives. The synthetic procedure employs mild reaction conditions and gives high chemoselectivity enabled by an inexpensive organodiselane catalyst. The presented approach offers a new synthetic pathway toward the core structures of phthalide natural products.
Pd-catalyzed olefination of perfluoroarenes with allyl esters
Li, Zejiang,Zhang, Yuexia,Liu, Zhong-Quan
supporting information; experimental part, p. 74 - 77 (2012/02/14)
An efficient Pd(II)-catalyzed direct olefination of perfluoroarenes with allyl esters is demonstrated. Under the typical conditions, the coupling reaction of fluorinated-arenes with allylic esters proceeded via a β-H elimination rather than a β-OAc elimin
