86153-21-1Relevant articles and documents
An unconventional synthesis of dibromophosphines
Wang, Lili,Zhang, Lujun,Shi, Hanyu,Duan, Zheng,Mathey, Fran?ois
supporting information, p. 2006 - 2008 (2013/09/24)
Dibromophosphines, RPBr2, are obtained by reaction of tetrabromomethane with 7-substituted 7-phosphanorbornenes in toluene at ca. 100 °C. The phosphanorbornenes are obtained in situ by cycloaddition of N-phenylmaleimide with 1-substituted 3,4-d
ZUR KENNTNIS DER ORGANOPHOSPHORVERBINDUNGEN, XXI. Darstellung von Organobromphosphanen aus RPCl2 und R2PCl durch Halogenaustausch.
Hinke, Axel,Kuchen, Wilhelm
, p. 93 - 98 (2007/10/02)
Several methods for the preparation of organobromophosphanes from RPCl2 and R2PCl by halogen exchange are described.In case of aryl compounds optimal results are obtained by equilibration of the chlorophosphanes with PBr3 followed by distillation or cryst