86175-47-5Relevant academic research and scientific papers
Ynones Merge Activation/Conjugate Addition of Chalcogenoborates ArE-Bpin (E=Se, S)
Civit, Marc G.,Sanz, Xavier,Vogels, Christopher M.,Bo, Carles,Westcott, Stephen A.,Fernández, Elena
supporting information, p. 3098 - 3103 (2015/11/03)
The "pull-push" effect of the Bpin moiety in ArE-Bpin reagents (E=Se, S) is demonstrated by the Lewis acid interaction with the carbonyl group of ynones and the concomitant delivery of ArSe or ArS to the electron-deficient alkyne with impressive stereosel
NUCLEOPHILIC THIYLATION OF DIARYLPROPYNONES. STEREOCHEMISTRY OF THE REACTION
Statsyuk, V. E.,Krasnov, V. L.,Korshunov, S. P.,Bodrikov, I. V.
, p. 408 - 414 (2007/10/02)
The stereochemical aspects of the reactions of diarylpropynones with alkali-metal thiolates and thiols activated by amines were investigated.The ratio between the adducts with the Z and E configurations under conditions with kinetic control and the config
