1443045-55-3Relevant academic research and scientific papers
Frustrated Lewis Pair Catalyzed S-H Bond Borylation
Rochette, étienne,Boutin, Hugo,Fontaine, Frédéric-Georges
supporting information, p. 2870 - 2876 (2017/08/21)
The frustrated Lewis pair (FLP) [NMe2-C6H4-BH2]2 is shown to catalyze the dehydrogenative borylation of thiols. The scope of the reaction, the experimental and computational investigation of the mecha
Thioboration of α,β-unsaturated ketones and aldehydes toward the synthesis of β-sulfido carbonyl compounds
Civit, Marc G.,Sanz, Xavier,Vogels, Christopher M.,Webb, Jonathan D.,Geier, Stephen J.,Decken, Andreas,Bo, Carles,Westcott, Stephen A.,Fernández, Elena
supporting information, p. 2148 - 2154 (2015/05/19)
Herein a direct β-sulfido carbonyl compound synthesis by the easy activation of RS-Bpin reagents with α,β-unsaturated ketones and aldehydes is reported. This convenient methodology can be performed at room temperature with no other additives. The key poin
Efficient ruthenium-catalysed S-S, S-Si and S-B bond forming reactions
Fernandez-Salas, Jose A.,Manzini, Simone,Nolan, Steven P.
supporting information, p. 5829 - 5831 (2013/07/19)
[RuCl(PPh3)2(3-phenylindenyl)] (1) has been shown to be an efficient catalyst in thiol dehydrogenative coupling to give disulfides. Moreover, an efficient procedure for the preparation of silylthioethers and thioboranes is presented. Complex 1 demonstrated a great ability to catalyse the coupling of thiols with silanes and boranes under mild conditions with excellent results (turnover number up to 200).
