861909-53-7

Basic information

• Product Name: R-3,3'-Bis(3,5-bis(methyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
• Synonyms: R-3,3'-Bis(3,5-bis(methyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate;(R)-3,3'-Bis(3,5-dimethylphenyl)-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate;(R)-3,3'-Bis[3,5-dimethylphenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate;2,6-bis(3,5-dimethylphenyl)-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide;(R)-3,3'-Bis(3,5-dimethylphenyl)-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate,,89%e.e.;(11bR)-2,6-Bis(3,5-dimethylphenyl)-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
• CAS NO: 861909-53-7
• Molecular Formula: C36H30O4P
• Molecular Weight: 557.594761
• Mol File: 861909-53-7.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 755.9±70.0 °C(Predicted)
• Appearance: white to light-yellow/Powder
• Density: 1.35±0.1 g/cm3(Predicted)
• PKA: 1.11±0.20(Predicted)
• CAS DataBase Reference: R-3,3'-Bis(3,5-bis(methyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate(CAS DataBase Reference)
• NIST Chemistry Reference: R-3,3'-Bis(3,5-bis(methyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate(861909-53-7)
• EPA Substance Registry System: R-3,3'-Bis(3,5-bis(methyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate(861909-53-7)

Safety Data

• Hazardous Substances Data: 861909-53-7(Hazardous Substances Data)

Usage

General Description

R-3,3'-Bis(3,5-bis(methyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate is a chemical compound used in the manufacturing of organic light-emitting diodes (OLEDs) and other electronic devices. It is a hydrogenphosphate derivative of a binaphthyl compound, which is characterized by its twisted and rigid structure. R-3,3'-Bis(3,5-bis(methyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate is known for its high thermal and chemical stability, making it suitable for use in a wide range of applications. R-3,3'-Bis(3,5-bis(methyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate exhibits high photoluminescence efficiency and can be used as a host material in OLED devices, where it helps to improve their performance and stability. Overall, this compound is valued for its unique properties and its potential to enhance the functionality of electronic devices.

Upstream product

• 75714-60-2 (S)-3-bromo-1-(3-bromo-2-methoxynaphthalen-1-yl)-2-methoxynaphthalene 
• 75640-87-8 (S)-2,2'-dimethoxy-1,1'-dinaphthyl 
• 215433-51-5 (S)-3,3’-bis(3,5-dimethylphenyl)-[1,1‘-binaphthalene]-2,2’-diol 

Relevant articles and documents

Erratum: Enantioselective organocatalytic Hantzsch synthesis of polyhydroquinolines (Organic Letters (2009) 11:14 (2957-2959) DOI: 10.1021/ol901114f)

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RETRACTED ARTICLE: Enantioselective organocatalytic hantzsch synthesis of polyhydroquinolines

The four-component Hantzsch reaction provides access to pharmaceutically important dihydropyridines. To expand the utility of this method, we have developed a route under organocatalytic conditions with good yields and excellent ee's. Through catalyst scr