862013-88-5

Basic information

• Product Name: 1,1'-bis(diphenylvinylsilyl)ferrocene
• Synonyms: 1,1'-bis(diphenylvinylsilyl)ferrocene
• CAS NO: 862013-88-5
• Molecular Weight: 602.706
• Mol File: 862013-88-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,1'-bis(diphenylvinylsilyl)ferrocene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1'-bis(diphenylvinylsilyl)ferrocene(862013-88-5)
• EPA Substance Registry System: 1,1'-bis(diphenylvinylsilyl)ferrocene(862013-88-5)

Safety Data

• Hazardous Substances Data: 862013-88-5(Hazardous Substances Data)

Upstream product

• 102-54-5 ferrocene 
• 109-72-8 n-butyllithium 
• 110-18-9 N,N,N,N,-tetramethylethylenediamine 
• 18419-53-9 vinyldiphenylchlorosilane 

Downstream Products

• 862013-90-9 (Z)-(1,1,4,4-tetraphenyl-1,4-disila-2,3-ethene)-[3]-ferrocenophane 

Relevant articles and documents

Highly selective synthesis and structural characterization of bis(silyl)-[3]-ferrocenophane derivatives

Bis(silyl)-[3]-ferrocenophanes have been easily prepared via ring-closing silylative coupling of 1,1′-bis(vinylsilyl)ferrocenes catalyzed by ruthenium hydride complexes. Dimethylvinylsilyl derivative 1 reacts under optimum conditions to give regioselectively and quantitatively disilacyclic product containing an exo-methylene (3) bond between two silicon atoms. The reaction with (diphenylvinylsilyl)ferrocene (2) permits stereoselective synthesis of the product with a cis-vinylene (4) bond between the silicon atoms. The structures of both products, which cannot be synthesized via a ring-closing metathesis procedure, have been confirmed using NMR and X-ray crystal structure methods.