86227-15-8Relevant academic research and scientific papers
Aerobic C?H Hydroxylation by Copper Imine Complexes: The Clip-and-Cleave Concept – Versatility and Limits
Specht, Pascal,Petrillo, Alexander,Becker, Jonathan,Schindler, Siegfried
, p. 1961 - 1970 (2021)
The intramolecular ligand hydroxylation of a series of copper(I) imine complexes during their reaction with dioxygen had been systematically studied. The so-called clip-and-cleave concept offers a facile way to oxygenate aldehydes or ketones. A copper(I)
One-pot synthesis of 1-(2-aminoethyl)-pyridyl-1-aryl methyl phosphonic acid monomethyl esters
Failla, Salvatore,Finocchiaro, Paolo,Haegele, Gerhard
, p. 83 - 90 (2007/10/03)
New phosphonate mono-methyl esters which are designed to have properties intermediate between the acid and the diesters and thus able to form discrete metal complexes with enhanced solubility in water, were synthesized using 2-(2-aminoethyl) pyridine as s
Synthesis and Crystal Structures of a Series of Amide Copper(II) Complexes
Alilou, El Houssine,Amadei, Edith,Giorgi, Michel,Pierrot, Marcel,Reglier, Marius
, p. 549 - 558 (2007/10/02)
The synthesis and structural determination by X-ray crystallography of four amide copper(II) complexes has been performed: NH(CH2)nPh>(solv)>2 (X = H, solv = H2O, n = 2 1 or 1 2; X = OH, solv = H2O, n = 2 3; solv = MeCN, n = 1 4).In all complexes the co-ordination around the copper atom is a more or less distorted square-based pyramid where the three ligands of the square are unchanged: one oxygen atom of the amide group and two nitrogen atoms of the pyridine nucleus and of the tertiary amine.The fourth ligand is a water molecule (1-3) or an acetonitrile solvent molecule (4).The axial ligand is the oxygen atom of the phenolic group in complexes 3 and 4, while in 1 and 2 this site is occupied by an oxygen atom of a triflate counter ion.
NAD(P)H MODELS-XVII. -- METAL ION CATALYZED REDUCTION OF IMINES BY 3,5-DIETHOXYCARBONYL-2,6-DIMETHYL-1,4-DIHYDROPYRIDINE (HANTZSCH ESTER)
Steevens, J. B.,Pandit, U. K.
, p. 1395 - 1400 (2007/10/02)
The reduction of imines by 3,5-diethoxycarbonyl-2,6-dimethyl-1,4-dihydropyridine, an NAD(P)H model, is catalyzed by Mg(2+) ions.Kinetic measurements of the reduction of a series of imines derived from substituted benzaldehydes, show a very small polar sub
