86228-85-5Relevant academic research and scientific papers
DISUBSTITUTED VINYLIDENE COMPLEXES OF IRON AND RUTHENIUM: NUCLEOPHILIC PROPERTIES OF η1-ACETYLIDE LIGANDS
Abbott, Steven,Davies, Stephen G.,Warner, Peter
, p. C65 - C68 (1983)
The η1-acetylide complexes (C5H5)ML2(CCR) (M=Fe, Ru; L=PPh3, L2=Ph2PCH2CH2PPh2) are nucleophilic at the β-carbon and react with a variety of mild electrophiles to yield the corresponding disubstituted vinylidene complexes PF6.
