DISUBSTITUTED VINYLIDENE COMPLEXES OF IRON AND RUTHENIUM: NUCLEOPHILIC PROPERTIES OF η1-ACETYLIDE LIGANDS

DOI: 10.1016/0022-328X(83)80211-3

Source and publish data:

Journal of Organometallic Chemistry p. C65 - C68 (1983)

Update date:2022-08-05

Topics:

Authors:

Abbott, Steven

Davies, Stephen G.

Warner, Peter

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(83)80211-3

The η¹-acetylide complexes (C5H5)ML2(C<*>CR) (M=Fe, Ru; L=PPh3, L2=Ph2PCH2CH2PPh2) are nucleophilic at the β-carbon and react with a variety of mild electrophiles to yield the corresponding disubstituted vinylidene complexes <(C5H5)ML2(=C=CRR')>PF6.

Full text of DOI:10.1016/0022-328X(83)80211-3

Products guided by the article

Product name:[(C₅H₅)Ru(P(C₆H₅)3)2(CC(C₂H₅)CH₂C₆H₅)]⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)Ru(P(C₆H₅)3)2(CC(C₂H₅)CH₂C₆H₅)]PF₆

Cas No:86228-85-5

R&D Labs maybe for 86228-85-5

Shanghai KFSL Pharmaceutical Technology Co.,Ltd.

Contact:+86-21-39971718

Address:859 jiadingchengliu shanghai
shijiazhuang baisheng chem co.; ltd

Contact:86-0311-80790826

Address:shijiazhuang hebei
Wuhan Jadechem International Trade Co.,Ltd.

website:http://www.jadechem-intl.com

Contact:+86-27-83527060

Address:Room 502,Building C11,Software new city No.8,Huacheng Avenue,East Lake High-tech development zone,Wuhan,Hubei,China
JenKem Technology Co., Ltd.

Contact:86-10-62983737; +86-10-51287608

Address:4/F Building C, 2 Shangdi Xinxi Road
Taiwan Surfactant Corp.

Contact:886 2 2541 0022

Address:8 Fl., No. 11, Sec. 1, Chung Shan North Rd., Taipei, Taiwan R.O.C.

Relevant to this article

Arylplatinum complexes with arylboronate ligands. Their preparation, structure, and relevance to transmetalation

Doi:10.1021/om049050t
(2005)
Synthesis and cross-coupling reactions of substituted 5-triflyloxyindoles

Doi:10.1021/jo050706h
(2005)
Metal-metal multiple bonds. 14. Synthesis, stereochemistry, and hydrogenation of protonated alkyne adducts of Cp₂Mo₂(CO)₄

Doi:10.1021/om50003a018
(1983)
The synthesis and studies of several [2.2.2]ferrocenophane derivatives

Doi:10.1246/bcsj.56.1143
(1983)
A simple synthesis of epimeric 2-azidoinosose derivatives

Doi:10.1016/S0008-6215(00)90964-9
(1983)
Reaction of (phenylenedioxy)trihalophosphoranes with arylacetylenes: VI. Regiochemistry of the reaction of 2,2,2-trihalo-5-methylbenzo[d][1,3,2] dioxaphospholes with arylacetylenes

Doi:10.1007/s11176-005-0108-2
(2004)

Article Doi