DISUBSTITUTED VINYLIDENE COMPLEXES OF IRON AND RUTHENIUM: NUCLEOPHILIC PROPERTIES OF η1-ACETYLIDE LIGANDS

DOI: 10.1016/0022-328X(83)80211-3

Source and publish data:

Journal of Organometallic Chemistry p. C65 - C68 (1983)

Update date:2022-08-05

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Authors:

Abbott, Steven

Davies, Stephen G.

Warner, Peter

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Article abstract of DOI:10.1016/0022-328X(83)80211-3

The η¹-acetylide complexes (C5H5)ML2(C<*>CR) (M=Fe, Ru; L=PPh3, L2=Ph2PCH2CH2PPh2) are nucleophilic at the β-carbon and react with a variety of mild electrophiles to yield the corresponding disubstituted vinylidene complexes <(C5H5)ML2(=C=CRR')>PF6.

Full text of DOI:10.1016/0022-328X(83)80211-3

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Product name:[(C₅H₅)Ru(P(C₆H₅)3)2(CC(C₂H₅)CH₂C₆H₅)]⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)Ru(P(C₆H₅)3)2(CC(C₂H₅)CH₂C₆H₅)]PF₆

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