862673-52-7Relevant academic research and scientific papers
Palladium-catalyzed allylic alkylation of optically active α-alkenyl-α-acyloxytrialkylsilane
Sakaguchi, Kazuhiko,Yamada, Takeshi,Ohfune, Yasufumi
, p. 5009 - 5012 (2005)
Pd-catalyzed inter- and intramolecular allylic alkylations of optically active α-alkenyl-α-acyloxysilanes are described. The reactions proceeded in a regio- and stereoselective manner to give the corresponding (E)-vinylsilanes in which the ee of the start
