Palladium-catalyzed allylic alkylation of optically active α-alkenyl-α-acyloxytrialkylsilane

Article abstract of DOI:10.1016/j.tetlet.2005.05.076

Pd-catalyzed inter- and intramolecular allylic alkylations of optically active α-alkenyl-α-acyloxysilanes are described. The reactions proceeded in a regio- and stereoselective manner to give the corresponding (E)-vinylsilanes in which the ee of the start