862806-04-0

Basic information

• Product Name: 1-(3,5-bis-benzyloxy-benzyloxymethyl)-2-methoxy-naphthalene
• Synonyms: 1-(3,5-bis-benzyloxy-benzyloxymethyl)-2-methoxy-naphthalene
• CAS NO: 862806-04-0
• Molecular Weight: 490.599
• Mol File: 862806-04-0.mol

Chemical Properties

• CAS DataBase Reference: 1-(3,5-bis-benzyloxy-benzyloxymethyl)-2-methoxy-naphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(3,5-bis-benzyloxy-benzyloxymethyl)-2-methoxy-naphthalene(862806-04-0)
• EPA Substance Registry System: 1-(3,5-bis-benzyloxy-benzyloxymethyl)-2-methoxy-naphthalene(862806-04-0)

Safety Data

• Hazardous Substances Data: 862806-04-0(Hazardous Substances Data)

Upstream product

• 40696-22-8 (2-methoxy-naphthalene-1-yl)-methanol 
• 24131-32-6 3,5-bis(benzyloxy)benzyl bromide 
• 67093-27-0 3,5-dibenzyloxybenzyl chloride 

Relevant articles and documents

Synthesis of dendritic phenol ether derivatives with a naphthalene core

A series of dendritic phenol ether derivatives with a naphthalene core were synthesized by the Williamson reaction as a coupling reaction between 1-hydroxymethylnaphthalene and polyether-based dendritic fragments in the presence of phase-transfer catalyst and alkali. The modified method for chlorination of dendritic benzyl alcohol was also developed using PPh3 and CCl4 as reagents and CH2Cl2/CCl4 as solvent. Copyright Taylor & Francis Group, LLC.

Photochemical generation of benzene-naphthalene biplanemers

A direct biplanemer synthesis could be achieved by a quantitative [4π+4π]photocycloaddition of benzyloxy substituted benzene and naphthalene rings (3d,e ? 4d,e). Since the products do not show a thermal Cope rearrangement-in contrast to the related longicyclic conjugated 9,10-benzotricyclo[4.2.2.22,5]dodeca-3,7,9-trienes-but a quantitative reverse reaction, they are interesting systems for an optical switching.