863222-52-0

Upstream product

• 2746-25-0 p-Methoxybenzyl bromide 
• 863222-51-9 4-(4-methoxybenzyloxy)-2-butynal 
• 207795-41-3 ethyl 4-(4-methoxybenzyloxy)but-2-ynoate 
• 824-94-2 p-methoxybenzyl chloride 
• 145222-40-8 4-(p-methoxybenzyloxy)-1-hydroxy-2-butyne 
• 4039-83-2 3-(4-methoxybenzyloxy)propyne 
• 199658-05-4 (2E)-4-[(4-methoxybenzyl)oxy]but-2-en-1-ol 

Downstream Products

• 1204484-39-8 (2S,3S)-4-(4-methoxybenzyloxy)-2-azidobutane-1,3-diol 
• 725715-24-2 (S)-1-((4-methoxybenzyl)oxy)pent-4-en-2-ol 
• 863222-53-1 (2R,3R)-2,3-epoxy-1-(4-methoxybenzyloxy)-4-pentene 
• 902168-68-7 (E)-ethyl 3-((2R,3R)-3-((4-methoxybenzyloxy)methyl)oxiran-2-yl)acrylate 
• 902168-70-1 1-Methoxy-4-((E)-(R)-2-methoxymethoxy-hex-3-en-5-ynyloxymethyl)-benzene 
• 902168-69-8 (E)-(R)-1-(4-Methoxy-benzyloxy)-hex-3-en-5-yn-2-ol 

Relevant academic research and scientific papers

Asymmetric synthesis of triacetyl-d-erythro-sphingosine and D-1-deoxyallonojirimycin via Miyashita C2 selective endo-mode azide opening of 2,3-epoxy alcohol

An efficient protocol for the asymmetric synthesis of triacetyl-d-erythro-sphingosine and D-1-deoxyallonojirimycin has been developed starting from commercially available propargyl alcohol. The key steps involved Sharpless asymmetric epoxidation and Miyashita C2 selective endo-mode azide opening of the 2,3-epoxy alcohol.

Total syntheses of the highly potent anti-cancer polyacetylenes, (S)-18-hydroxyminquartynoic acid, (S)-minquartynoic acid and (E)-15,16-dihydrominquartynoic acid

The total syntheses of three polyacetylenic natural products, (S)-18-hydroxyminquartynoic acid (1), (S)-minquartynoic acid (2) and (E)-15,16-dihydrominquartynoic acid (3), has been achieved. The Cadiot-Chodkiewicz cross-coupling reaction was used as the k

Synthesis of the EF-ring segment of ciguatoxin CTX1B based on novel regioselective reduction of unsaturated cyanohydrins and ring-closing olefin metathesis

Aiming at a convergent total synthesis of ciguatoxin CTX1B, its EF-ring segment has been synthesized. During the synthesis, a novel method for the construction of branched ethers, based on regioselective reduction of γ-alkoxy β,γ-unsaturated α-silyloxy ni

Stereospecific synthesis of α,ω-cis- and α,ω-trans-disubstituted oxepanes

An efficient and versatile method for the stereospecific construction of α,ω-cis- and α,ω-trans-disubstituted oxepane skeletons is described. Cyclization of the hydroxy epoxides promoted by a (Bu3Sn)2O/ Zn(OTf)2 system proceeded via an S(N)2 process and exo mode selectivity regardless of the configuration of the hydroxyl and the epoxy groups to provide the corresponding oxepanes in excellent yields. (C) 2000 Elsevier Science Ltd.