863609-43-2Relevant academic research and scientific papers
A bromine adduct of 2,3,6,7,14,15-hexamethyl-9,10-distibatriptycene. The first stibonium-stiborate zwitterion
Uchiyama, Yosuke,Yamamoto, Gaku
, p. 966 - 967 (2005)
2,3,6,7,14,15-Hexamethyl-9,10-distibatriptycene (3) reacted with bromine to give an adduct 4 with the composition of 3·2Br2. X-ray structure analysis and 1H NMR studies revealed that the bromine adduct 4 forms an intramolecular salt composed of a tetracoordinate bromostibonium ion moiety, R3SbBr+, and a hexacoordinate tribromostiborate ion moiety, R3SbBr3-, both in the crystalline state and in solution. Copyright
Bromine adducts of 9,10-diheteratriptycene derivatives
Uchiyama, Yosuke,Sugimoto, Jun,Shibata, Munenori,Yamamoto, Gaku,Mazaki, Yasuhiro
, p. 819 - 828 (2009/12/25)
2,3,6,7,14,15-Hexamethyl-9,10-diphosphatriptycene (1), 2,3,6,7,14,15- hexamethyl-9-phospha-10-stibatriptycene (2), and 2,3,6,7,14,15-hexamethyl-9,10- distibatriptycene (3) were synthesized and their molecular structures were determined by X-ray crystallog
