864182-80-9

Upstream product

• 58879-34-8 (S)-5-tosyloxypentan-4-olide 
• 85428-31-5 3-(S)-oxiranyl-propionic acid methyl ester 
• 3393-45-1 5,6-dihydro-pyran-2-one 
• 864270-13-3 5-[(2E)-4-(tert-butyldimethylsilyloxy)-2-methylbut-2-enyl]-3-{(3S)-1-hydroxy-4-methyl-3-[(5-methylene-2-phenyl-1,3-dioxan-4-yl)methyl]pent-4-enyl}-3-(phenylseleno)dihydrofuran-2(3H)-one 
• 864270-17-7 (3R)-1-{5-[(2E)-4-(tert-butyldimethylsilyloxy)-2-methylbut-2-enyl]-2-oxo-2,5-dihydrofuran-3-yl}-4-methyl-3-[(5-methylene-2-phenyl-1,3-dioxan-4-yl)methyl]pent-4-enyl acetate 
• 864270-14-4 5-[(2E)-4-(tert-butyldimethylsilyloxy)-2-methylbut-2-enyl]-3-{(3S)-1-hydroxy-4-methyl-3-[(5-methylene-2-phenyl-1,3-dioxan-4-yl)methyl]pent-4-enyl}furan-2(5H)-one 
• 864270-19-9 (E)-4-{(R)-4-[(R)-1-Acetoxy-4-methyl-3-(5-methylene-2-phenyl-[1,3]dioxan-4-ylmethyl)-pent-4-enyl]-5-oxo-2,5-dihydro-furan-2-yl}-3-methyl-but-2-enoic acid 
• 864270-15-5 (3R)-1-{5-[(2E)-4-hydroxy-2-methylbut-2-enyl]-2-oxo-2,5-dihydrofuran-3-yl}-4-methyl-3-[(5-methylene-2-phenyl-1,3-dioxan-4-yl)methyl]pent-4-enyl acetate 
• 864270-18-8 (3R)-4-methyl-3-[(5-methylene-2-phenyl-1,3-dioxan-4-yl)methyl]-1-{5-[(2E)-2-methyl-4-oxobut-2-enyl]-2-oxo-2,5-dihydrofuran-3-yl}pent-4-enyl acetate 
• 864182-70-7 (4R)-2-(phenylselenyl)-6-methyl-8-(tert-butyldimethylsilyloxy)oct-6-en-4-olide 
• 864182-79-6 (3S)-3-isopropenyl-5,7-O-benzylidene-6-methylene-heptanol 
• 864182-72-9 (4S)-methyl 4-hydroxy-6-methyl-8-(tert-butyldimethylsilyloxy)oct-6-enoate 
• 864182-71-8 (3S)-3-isopropenyl-5,7-O-benzylidene-6-(methylene)heptanal 
• 864182-73-0 (4S)-6-methyl-8-(tert-butyldimethylsilyloxy)oct-6-en-4-olide 

Relevant academic research and scientific papers

Synthetic studies towards furanocembrane diterpenes. A total synthesis of bis-deoxylophotoxin

Synthetic approaches to the furanocembrane family of natural products, e.g. lophotoxins, pukalides, bipinnatins, based on: i) an intramolecular cyclisation of an α,β-unsaturated acyl radical intermediate into a conjugated enone, viz. 18 → 17, and ii) an i