864369-29-9

Upstream product

• 90719-30-5 (4S)-3-((E)-2-butenoyl)-4-benzyl-2-oxazolidinone 
• 120-14-9 3,4-dimethoxy-benzaldehyde 

Downstream Products

• 689277-87-0 (+)-(2S,5S)-4-benzyl-3-{2-[(tert-butyldimethylsilanyloxy)-(3,4-dimethoxyphenyl)methyl]but-3-enoyl}oxazolidin-2-one 
• 80287-36-1 α-conidendrin monomethyl ether 
• 689277-90-5 (-)-(2S,5S)-4-[(tert-butyldimethylsilanyloxy)-(3,4-dimethoxyphenyl)methyl]-3-[4-(tert-butyldimethylsilanyloxy)-3-methoxybenzyl]dihydrofuran-2-one 
• 689277-89-2 (-)-(2S,5S)-thiocarbonic acid O-{2-[(tert-butyldimethylsilanyloxy)-(3,4-dimethoxyphenyl)methyl]but-3-enyl} ester O-[4-(tert-butyldimethylsilanyloxy)-3-methoxyphenyl] ester 
• 689277-88-1 (-)-(2S,5S)-2-[(tert-butyldimethylsilanyloxy)-(3,4-dimethoxyphenyl)methyl]but-3-en-1-ol 
• 74861-40-8 (7'S,8R,8'R)-4,7'-dihydroxy-3,3',4'-trimethoxylignano-9,9'-lactone 
• 26687-82-1 Arctigenin 
• 864369-19-7 (S)-4-Benzyl-3-[(6S,7S)-7-(3,4-dimethoxy-phenyl)-2,2-dimethyl-2,3,6,7-tetrahydro-[1,2]oxasilepine-6-carbonyl]-oxazolidin-2-one 

Relevant academic research and scientific papers

Stereocontrolled assembly of tetrasubstituted tetrahydrofurans: A concise synthesis of virgatusin

(Chemical Equation Presented) The condensation of substituted allylsiloxanes with aldehydes leads to the highly stereoselective construction of 2,3,4,5-tetrasubstituted tetrahydrofurans. With electron-rich aryl and α,β-unsaturated aldehydes as substrates,

Radical carboxyarylation approach to lignans. Total synthesis of (-)-arctigenin, (-)-matairesinol, and related natural products

Total syntheses of seven biologically important lignan natural products, including (-)-arctigenin, (-)-matairesinol, and (-)α-conidendrin, by way of a highly stereoselective domino radical sequence is presented. The reported stereochemistry of the natural product 7-hydroxyarctigenin is shown to be erroneous; a diastereoisomeric structure is assigned to the natural product.