864429-34-5

Upstream product

• 109-97-7 pyrrole 
• 653-37-2 perfluorobenzaldehyde 
• 603-35-0 triphenylphosphine 
• 167482-91-9 5-(pentafluorophenyl)dipyrromethane 
• 292164-60-4 5,10-bis(pentafluorophenyl)tripyrrane 
• 1266248-85-4 4-methyl-N-((perfluorophenyl)methylene)benzenesulfonamide 

Downstream Products

• 500116-50-7 [(C₃₀H₁₀N₆O₂)(C₆F₅)6]Cu₂ 
• 1254708-14-9 [nickel(II)[28]hexaphyrin(1.1.1.1.1.1)] 
• 857379-42-1 (meso-hexakis(pentafluorophenyl)-[26]-hexaphyrin(1.1.1.1.1.1)-6H)Au₂ 

Relevant academic research and scientific papers

meso-Substituted expanded porphyrins: New and stable hexaphyrins

New hexapyrrolic macrocycles have been synthesized and characterized by UV-VIS, mass and NMR spectroscopy and X-ray crystallography.

BODIPY-hexaphyrin hybrids

Expand your horizon: BODIPY-appended [28]-and [26]hexaphyrins (see figure) were prepared and the efficient intramolecular excitation energy transfer from the BODIPY part to the hexaphyrin part was revealed in both hybrids. Importantly this is the first ex

Comparative photophysics of [26]- and [28]hexaphyrins(1.1.1.1.1.1): Large two-photon absorption cross section of aromatic [26]hexaphyrins(1.1.1.1.1.1)

We have explored the electronic natures of representative expanded porphyrins, [26]- and [28]-hexaphyrins, to investigate the interplay between the aromaticity and antiaromaticity that is brought by two electron oxidation/reduction processes. The excited

Nonlinear optical properties and excited-state dynamics of highly symmetric expanded porphyrins

A strong correlation among calculated Nucleus-Independent Chemical Shift (NICS) values, molecular planarity, and the observed two-photon absorption (TPA) values was found for a series of closely matched expanded porphyrins. The expanded porphyrins in ques

meso-porphyrinyl-substituted porphyrin and expanded porphyrins

(Chemical Equation Presented) A series of meso-porphyrinyl-substituted expanded porphyrins were prepared from the 1:1 acid-catalyzed condensation reaction of 4-porphyrinyl-2,3,5,6-tetrafluorobenzaldehyde and pyrrole.

A new reagent for the synthesis of [26]hexaphyrin: N-sulfonyl aldimine

The selective synthesis of [26]hexaphyrin(1.1.1.1.1.1) has been achieved by the reaction of meso-substituted tripyrrane and N-sulfonyl aldimine. The protocol is simple and requires only a catalytic amount of copper(II) triflate under mild reaction conditions.

Sulfonated graphenes catalyzed synthesis of expanded porphyrins and their supramolecular interactions with pristine graphene

A newer synthesis of sulfonic acid functionalized graphenes have been developed, which have been characterized, examined as heterogeneous solid acid carbocatalyst in the synthesis of selected expanded porphyrins in different reaction conditions. This envi

Facile synthesis of large meso-pentafluorophenyl-substituted expanded porphyrins

Acid-catalyzed condensation of meso-pentafluorophenyl dipyrromethane 1 (100 mM) and pentafluorobenzaldehyde 2 (100 mM) at 0 °C gave a series of expanded porphyrins with even number of pyrrolic subunits up to octadecaphyrin-(1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1) 18 in improved yields, particularly for larger expanded porphyrins. The solid-state structure of decaphyrin(1.1.1.1.1.1.1.1.1.1) 10 was revealed by X-ray diffraction analysis to be a crescent-like conformation. The Soret-like absorption bands are increasingly redshifted as the size of the ring increases, but such a trend becomes nearly saturated for hexadecaphyrin-(1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1) 16 and 18, which exhibit bands in the near-infrared region at 939 and 953 nm, respectively. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.

[40]Nonaphyrin(1.1.1.1.1.1.1.1.1) and its heterometallic complexes with palladium-carbon bonds

meso-Pentafluorophenyl-substituted [40]nonaphyrin-(1.1.1.1.1.1.1.1.1) 3 has been prepared by using a stepwise ring-size-selective synthesis, and has been reduced with NaBH4 to [42]nonaphyr-in(1.1.1.1.1.1.1.1.1) 5. Structurally, 3 is characteriz

Oxidation of hydroquinones with meso-hexakispentafluorophenyl [26]hexaphyrin(1.1.1.1.1.1)

Treatment of various hydroquinones and catechols with meso- pentafluorophenyl [26]hexaphyrin(1.1.1.1.1.1) provided the corresponding quinones quantitatively. The Royal Society of Chemistry 2006.