meso-hexakis(pentafluorophenyl)-[26]-hexaphyrin(1.1.1.1.1.1)

Base Information

• Chemical Name: meso-hexakis(pentafluorophenyl)-[26]-hexaphyrin(1.1.1.1.1.1)
• CAS No.: 864429-34-5
• Molecular Formula: C₆₆H₁₄F₃₀N₆
• Molecular Weight: 1460.83
• Mol file: 864429-34-5.mol

Synonyms:meso-hexakis(pentafluorophenyl)-[26]-hexaphyrin(1.1.1.1.1.1)

Chemical Property of meso-hexakis(pentafluorophenyl)-[26]-hexaphyrin(1.1.1.1.1.1)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of meso-hexakis(pentafluorophenyl)-[26]-hexaphyrin(1.1.1.1.1.1)

There total 15 articles about meso-hexakis(pentafluorophenyl)-[26]-hexaphyrin(1.1.1.1.1.1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

meso-hexakis(pentafluorophenyl)[28]hexaphyrin → mesohexakis(pentafluorophenyl)[26]hexaphyrin (864429-34-5)

Guidance literature:

With 2,3-dicyano-5,6-dichloro-p-benzoquinone;

DOI:10.1021/ol048953f

Reference yield: 30.0%

perfluorobenzaldehyde (653-37-2) + 5,10-bis(pentafluorophenyl)tripyrrane (292164-60-4) → C99H22F45N9 + C132H32F60N12 + tetrakis(pentafluorophenyl)porphyrin (25440-14-6) + mesohexakis(pentafluorophenyl)[26]hexaphyrin (864429-34-5)

Guidance literature:

perfluorobenzaldehyde; 5,10-bis(pentafluorophenyl)tripyrrane; With methanesulfonic acid; In dichloromethane; for 2h;

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; at 20 ℃; Further stages. Further byproducts.;

DOI:10.1002/chem.200601304

Reference yield: 28.0%

perfluorobenzaldehyde (653-37-2) + 5-(pentafluorophenyl)dipyrromethane (167482-91-9) → C88H20F40N8 + tetrakis(pentafluorophenyl)porphyrin (25440-14-6) + mesohexakis(pentafluorophenyl)[26]hexaphyrin (864429-34-5)

Guidance literature:

With sulfonated graphene; In 1,2-dichloro-benzene; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1007/s12039-014-0731-8

upstream raw materials:

pyrrole

perfluorobenzaldehyde

triphenylphosphine

5-(pentafluorophenyl)dipyrromethane

Downstream raw materials:

C₆₈H₁₈F₃₀N₆