864514-98-7Relevant academic research and scientific papers
A general synthesis of quinone ammonium salts
Wiedenfeld, David,Minton, Mark A.,Glass, David R.,Nesterov, Vladimir N.,Nsamenang, Kila D.,Han, Dong
, p. 1611 - 1618 (2007/10/03)
A three-step procedure has been developed to convert substituted p-dimethoxybenzenes to quinone ammonium salts. Five examples of quinone ammonium salts have been prepared with this procedure. In the first step, the aromatic species is reacted with N-(hydr
Bis(2,5-dimethoxy-4-methylphenyl)methane and bis(2,5-dimethoxy-3,4,6-trimethylphenyl)methane.
Wiedenfeld, David J,Nesterov, Vladimir N,Minton, Mark A,Glass, David R
, p. o700-702 (2007/10/03)
Bis(2,5-dimethoxy-4-methylphenyl)methane, C(19)H(24)O(4), (IIa), was obtained and characterized as a minor product from the reaction of toluhydroquinone dimethyl ether (1,4-dimethoxy-2-methylbenzene) with N-(hydroxymethyl)trifluoroacetamide. Similarly, bis(2,5-dimethoxy-3,4,6-trimethylphenyl)methane, C(23)H(32)O(4), (IIb), was prepared from the corresponding reaction of trimethylhydroquinone dimethyl ether (2,5-dimethoxy-1,3,4-trimethylbenzene). The molecules of (IIa) and (IIb) each lie on a twofold axis passing through the methylene group. The dihedral angle between the planar phenyl rings is 73.4 (1) degrees in (IIa) and 77.9 (1) degrees in (IIb). The external bond angles around the bridging methylene group are 116.6 (2) and 117.3 (2) degrees for (IIa) and (IIb), respectively. In (IIa), the methoxy substituents lie in the plane of the ring and are conjugated with the aromatic system, whereas in (IIb), they are almost perpendicular to the phenyl ring and are positioned on opposite sides.
