124292-06-4

Upstream product

• 917-54-4 methyllithium 
• 107108-54-3 ((Z)-1-Benzenesulfonyl-2-(S)-oxiranyl-vinyl)-trimethyl-silane 
• 96689-27-9 1-Phenylsulfonyl-3-methyl-but-3-en 
• 49639-05-6 1-(phenylsulfonyl)-2-methyl-2-propene 
• 96689-26-8 1-hydroxy-2-methyl-3-(phenylsulfonyl)propane 
• 83802-87-3 2-methyl-3-(phenylsulfonyl)propanal 
• 107108-48-5 [(Z)-2-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-1-phenylsulfanyl-vinyl]-trimethyl-silane 
• 107108-49-6 (Z)-(S)-4-Phenylsulfanyl-4-trimethylsilanyl-but-3-ene-1,2-diol 
• 107108-52-1 (Z)-(S)-1-Chloro-4-phenylsulfanyl-4-trimethylsilanyl-but-3-en-2-ol 
• 62761-90-4 α,α-bis(trimethylsilyl)methylphenyl sulfide 

Downstream Products

• 86537-31-7 2-exo-methyl-1-(phenylsulfonyl)bicyclo<1.1.0>butane 
• 96745-07-2 2-endo-methyl-1-(phenylsulfonyl)bicyclo<1.1.0>butane 

Relevant academic research and scientific papers

ACYCLIC STEREOCONTROL BY HETEROCONJUGATE ADDITION--4 ANTI-DIASTEREOSELECTION BY A β-CHELATION EFFECT

High selectivity in heteroconjugate addition for C-C bond formation with complete syn-diastereoselection has been attributed to the chelation effect between the α-oxygen atom of the substrate and the nucleophile anions through metal cations.Herein is desc

Stereochemistry of Addition of Organocopper Reagents and of the Hydride Ion to 1-(Arylsulfonyl)bicyclobutanes

Addition of methylmagnesium iodide/cuprous iodide or of lithium dimethylcuprate to 2-exo- and 2-endo-methyl-1-(phenylsulfonyl)bicyclobutane and determination of the relative geometry of the methyls in the 2,3-dimethylcyclobutanes obtained allowed u