86537-63-5

Basic information

• Product Name: Carbonic acid, ethyl 2-phenyl-2-propenyl ester
• CAS NO: 86537-63-5
• Molecular Formula: C12H14O3
• Molecular Weight: 206.241
• Mol File: 86537-63-5.mol

Chemical Properties

• CAS DataBase Reference: Carbonic acid, ethyl 2-phenyl-2-propenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbonic acid, ethyl 2-phenyl-2-propenyl ester(86537-63-5)
• EPA Substance Registry System: Carbonic acid, ethyl 2-phenyl-2-propenyl ester(86537-63-5)

Safety Data

• Hazardous Substances Data: 86537-63-5(Hazardous Substances Data)

Upstream product

• 6006-81-1 3-hydroxy-2-phenylpropene 
• 541-41-3 chloroformic acid ethyl ester 

Downstream Products

• 5155-87-3 3-phenylbut-3-enoic acid 
• 1415610-59-1 (S)-4-hydroxy-3-phenylbutanoic acid phenyl amide 
• 21298-87-3 3-phenyl-3-butenoic acid phenyl amide 
• 1415610-34-2 (S)-4-(4,4,6-trimethyl-1,3,2-dioxaborato)-3-phenylbutanoic acid phenyl amide 
• 1412908-41-8 N-trifluoroacetyl-(S)-phenylalanyl-(R)-(2-phenylallyl)-glycyl-(S)-prolinanilide 
• 1412908-42-9 N-trifluoroacetyl-(S)-phenylalanyl-(S)-(2-phenylallyl)-glycyl-(S)-prolinanilide 
• 1273503-75-5 (2S)-2-(2,2,2-trifluoroacetamido)-N-[1-(3,4-dihydroquinolin-1(2H)-yl)-1-oxo-4-phenylpent-4-en-2-yl]-3-phenylpropanamide 
• 1134-71-0 ethyl 3-phenylbutanoate 
• 5633-64-7 ethyl 3-phenyl-3-butenoate 
• 128318-85-4 1-(1-azidoprop-2-en-2-yl)benzene 

Relevant articles and documents

Stereoselective Modification of N-(α-Hydroxyacyl)-glycinesters via Palladium-Catalyzed Allylic Alkylation

N-(α-Hydroxyacyl)-glycinesters can be used as excellent nucleophiles in Pd-catalyzed allylic alkylation. The method allows for the stereoselective introduction of a wide range of side chains, including highly functionalized ones. Both diastereomers can be accessed through variation of the reaction conditions. Furthermore, the use of stannylated carbonates introduces vinylstannane motifs, which are eligible for subsequent C-C coupling reactions.

γ-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes

Directed catalytic asymmetric hydroborations of 1,1-disubstituted alkenes afford γ-dioxaborato amides and esters in high enantiomeric purity (90-95% ee). The Royal Society of Chemistry 2012..

Optimization of asymmetric hydrogenation of 3-phenyl-3-butenoic acid catalyzed by rhodium(I)-4,5-bis-2,2-dimethyldioxolane (DIOP)

Enantioselective, homogeneous hydrogenation of 3-phenyl-3-butenoic acid (1) has extensively been examined in the presence of the rhodium(I)/4,5-bis-2,2-dimethyldioxolane (DIOP) catalyst systems.Optimization of the reaction conditions was undertaken mainly by controlling effects of added tertiary amines as well as solvent polarities on the enantio-selectivity of the product.The best asymmetric yield (85.1percent e.e.) was attained when the hydrogenation was carried out in the presence of triethylamine (5 molpercent) in 75percent aqueous methanol using a neutral rhodium-DIOP catalyst.