86559-21-9

Basic information

• Product Name: 1-isocyano-1-methyl-cyclohexane
• Synonyms: 1-isocyano-1-methyl-cyclohexane
• CAS NO: 86559-21-9
• Molecular Weight: 123.198
• Mol File: 86559-21-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-isocyano-1-methyl-cyclohexane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-isocyano-1-methyl-cyclohexane(86559-21-9)
• EPA Substance Registry System: 1-isocyano-1-methyl-cyclohexane(86559-21-9)

Safety Data

• Hazardous Substances Data: 86559-21-9(Hazardous Substances Data)

Upstream product

• 7677-24-9 trimethylsilyl cyanide 
• 1192-37-6 methylenecyclohexane 
• 591-49-1 1-methylcyclohex-1-ene 
• 590-67-0 1-Methylcyclohexanol 

Downstream Products

• 1230074-62-0 [Ru(CN)2(CH₃C₆H₁₀NC)4] 
• 1230074-62-0 [Ru(CN)2(CH₃C₆H₁₀NC)4] 
• 1230074-61-9 [Fe(CN)2(CH₃C₆H₁₀NC)4] 
• 1230074-61-9 [Fe(CN)2(CH₃C₆H₁₀NC)4] 
• 1559070-68-6 N-(1-methylcyclohexyl)phenanthridin-6-amine 
• 62718-34-7 1-methylcyclohexanecarbonitrile 

Relevant articles and documents

A direct conversion of alkenes to isocyanides

Treatment of alkenes with silver salts (AgClO4, AgBF4, or AgOTf) and trimethylsilyl cyanide (TMSCN) in dichloromethane followed by hydrolysis affords the corresponding isocyanides directly in high yields. The addition of the isocyano function is carried out in accordance with Markovnikov's rule.