Synlett p. 288 - 290 (1999)
Update date:2022-09-26
Topics:
Kitano, Yoshikazu
Chiba, Kazuhiro
Tada, Masahiro
Treatment of alkenes with silver salts (AgClO4, AgBF4, or AgOTf) and trimethylsilyl cyanide (TMSCN) in dichloromethane followed by hydrolysis affords the corresponding isocyanides directly in high yields. The addition of the isocyano function is carried out in accordance with Markovnikov's rule.
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