86565-31-3Relevant articles and documents
REGIOSPECIFIC PREPARATION OF THERMODYNAMIC SILYL ENOL ETHERS USING BROMOMAGNESIUM DIALKYLAMIDES
Krafft, M. E.,Holton, Robert A.
, p. 1345 - 1348 (1983)
Thermodynamic silyl enol ethers are regiospecifically generated in high yield from cyclic ketones, bromomagnesium diisopropylamide (BMDA) and trimethylsilyl chloride.
Preparation of a New, Highly Reactive Form of Iron(0) and Its Use in Deprotonation of Carbonyl Compounds
Krafft, Marie E.,Holton, Robert A.
, p. 3669 - 3670 (2007/10/02)
A new, highly reactive form of zerovalent iron, prepared from the reaction of methylmagnesium bromide and ferric chloride, has been found to deprotonate cyclic unsymmetrical ketones in the presence of trimethylsilyl chloride to give thermodynamic (more substituted) silyl enol ethers regiospecifically.