SYNTHESIS AND CRYSTAL STRUCTURE OF THE dihapto-BONDED PHENYLISOTHIOCYANATE COMPLEX 2-SCNPh)>*0.5CH2Cl2

DOI: 10.1016/S0022-328X(00)98764-3

Source and publish data:

Journal of Organometallic Chemistry p. C29 - C31 (1983)

Update date:2022-08-05

Topics:

Authors:

Bianchini, Claudio

Masi, Dante

Mealli, Carlo

Meli, Andrea

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Article abstract of DOI:10.1016/S0022-328X(00)98764-3

The complex <(triphos)Ni(η²-SCNPh)> (triphos=1,1,1-tris(diphenylphosphinomethyl)ethane) is obtained from the reaction of the nickel(0) complex <(triphos)Ni(η²-CS2)> with phenylisothiocyanate.An X-ray crystal structure determination has shown that the nickel atom is five-coordinated by the three phosphorus atoms of triphos and the carbon and sulfur atoms of a SNCPh molecule.

Full text of DOI:10.1016/S0022-328X(00)98764-3

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