86613-76-5Relevant academic research and scientific papers
An Improved Synthesis of O-Benzoyl Protected Hydroxamates
Wang, Queenie Xianghong,King, Jennifer,Phanstiel IV, Otto
, p. 8104 - 8108 (2007/10/03)
Several primary amines (R-NH2) were converted to their corresponding O-benzoyl protected hydroxamates under biphasic conditions. The intermediate (benzoyloxy)amines (R-NHOCOPh) were generated using benzoyl peroxide dissolved in CH2Cl2 and an aqueous carbonate buffer (pH 10.5) at room temperature. Subsequent acylation with R'COCl gave the protected hydroxamates (R'CONROCOPh) in good overall yields (56-89%).
THE CONFORMATIONAL BEHAVIOUR OF HYDROXAMIC ACIDS
Kolasa, T.
, p. 1753 - 1760 (2007/10/02)
N-Formyl-N-alkylhydroxylamines, N-formyl-α-N-hydroxyamino-acid esters and some N-acetyl analogues exist as Z/E equilibrium mixtures, as shown by H-NMR and IR.The dependence of the Z/E ratio on the nature of N-substituents, acyl groups and solvent was stud
