86631-63-2Relevant academic research and scientific papers
PHOTOSTIMULATED REACTION OF ARYL IODIDES WITH 2-NAPHTHOXIDE IONS BY THE SRN1 MECHANISM
Pierini, A. B.,Baumgartner, M. T.,Rossi, R. A.
, p. 3429 - 3432 (1988)
The photostimulated reactions of p-iodoanisole (2) and 1-iodonaphthalene (7) with 2-naphthoxide ions in liquid ammonia gave the corresponding 1-aryl-2-naphthols as the only substitution product.These reactions are proposed to proceed via the SRN1 mechanism for nucleophilic aromatic substitution.
Steric effects of nucleophile-radical coupling reaction. Determination of rate constants for the reaction of aryl radicals with 2-naphthoxide anion
Tempesti, Tomas C.,Pierini, Adriana B.,Baumgartner, Maria T.
experimental part, p. 1523 - 1528 (2009/10/30)
The absolute rate constants for the reaction of different aryl radicals with 2-naphthoxide anion were determined using an indirect method, a competition of the coupling reaction with the H-atom abstraction. We here show that the radical-ambident nucleophi
