86654-59-3

Upstream product

• 85315-67-9 3-C-(benzyloxymethyl)-3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-allofuranose 
• 85315-68-0 3-C-(benzyloxymethyl)-3-deoxy-1,2-O-isopropylidene-α-D-allofuranose 
• 100-44-7 benzyl chloride 
• 69832-48-0 ((3aR,5S,6R,6aR)-tetrahydro-2,2-dimethyl-5-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)furo[2,3-d][1,3]dioxol-6-yl)methanol 
• 85315-69-1 3-C-(benzyloxymethyl)-3-deoxy-1,2-O-isopropylidene-6-O-tosyl-α-D-allofuranose 
• 21665-16-7 3-deoxy-1,2:5,6-di-O-isopropylidene-3-C-methylene-α-D-ribo-hexofuranose 
• 69832-48-0 3-C-deoxy-3-C-hydroxymethyl-1,2;5,6-di-O-isopropylidene-α-D-allo-furanose 

Downstream Products

• 98039-21-5 3-C-benzyloxymethyl-3,5,6-trideoxy-1,2-O-isopropylidene-5-C-(4-methoxybenzyloxymethyl)-α-D-ribo-hex-5-enofuranose 
• 98039-29-3 3-C-benzyloxymethyl-3-deoxy-1,2-O-isopropylidene-6-O-(4-methoxybenzyl)-α-D-ribo-hexofuranos-5-ulose 
• 98039-23-7 3-C-benzyloxymethyl-3,5-dideoxy-1,2-O-isopropylidene-6-O-(4-methoxybenzyl)-5-C-methyl-α-D-allofuranose 
• 98039-22-6 3-C-benzyloxymethyl-3,5-dideoxy-1,2-O-isopropylidene-6-O-(4-methoxybenzyl)-5-C-methyl-β-L-talofuranose 
• 98039-20-4 3-C-benzyloxymethyl-3-deoxy-1,2-O-isopropylidene-6-O-(4-methoxybenzylidene)-α-D-allofuranose 
• 86654-53-7 (2R,3S,4R)-1-Benzyloxy-5-(4-methoxy-benzyloxy)-2,4-dimethyl-pentan-3-ol 
• 86654-61-7 (S)-2-((3aR,5R,6R,6aR)-6-Benzyloxymethyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-propan-1-ol 
• 86654-61-7 (R)-2-((3aR,5R,6R,6aR)-6-Benzyloxymethyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-propan-1-ol 
• 86654-62-8 (2R,3R,4R)-1-benzyloxy-3-hydroxy-2-hydroxymethyl-5-(4-methoxybenzyloxy)-4-methylpentane 
• 86654-60-6 (3aR,5S,6R,6aR)-6-Benzyloxymethyl-5-isopropenyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole 

Relevant academic research and scientific papers

Chiral Synthesis of Polyketide-derived Natural Products. Part 5. Synthesis of a Chiral Segment Corresponding to the C-1-C-5 Unit of Erythromycin A from D-Glucose

As a right-hand segment with three consecutive chiral centres corresponding to the C-1-C-5 unit of erythromycin A (1), (2S,3R,4S)-3,5-isopropylidenedioxy-2,4-dimethylpentanal (32) was synthesized from D-glucose (5) by application of MPM (4-methoxybenzyl)

STEREOCONTROLLED SYNTHESIS OF CHIRAL SYNTHONS FOR POLYKETIDE-DERIVED NATURAL PRODUCTS

Four chiral synthons having three consecutive asymmetric centers for the synthesis of macrolide and polyether antibiotics were synthesized from D-glucose via stereoselective hydroboration.