85315-67-9

Basic information

• Product Name: 3-C-(benzyloxymethyl)-3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-allofuranose
• Synonyms: 3-C-(benzyloxymethyl)-3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-allofuranose
• CAS NO: 85315-67-9
• Molecular Weight: 364.439
• Mol File: 85315-67-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 3-C-(benzyloxymethyl)-3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-allofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 3-C-(benzyloxymethyl)-3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-allofuranose(85315-67-9)
• EPA Substance Registry System: 3-C-(benzyloxymethyl)-3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-allofuranose(85315-67-9)

Safety Data

• Hazardous Substances Data: 85315-67-9(Hazardous Substances Data)

Upstream product

• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 2847-00-9 1,2:5,6-di-O-isopropylidene-α-D-hexofuran-3-ulose 
• 69832-48-0 ((3aR,5S,6R,6aR)-tetrahydro-2,2-dimethyl-5-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)furo[2,3-d][1,3]dioxol-6-yl)methanol 
• 100-44-7 benzyl chloride 

Downstream Products

• 85315-69-1 3-C-(benzyloxymethyl)-3-deoxy-1,2-O-isopropylidene-6-O-tosyl-α-D-allofuranose 
• 85315-70-4 3-C-(benzyloxymethyl)-3,6-dideoxy-1,2-O-isopropylidene-α-D-allofuranose 
• 314061-33-1 Methanesulfonic acid (R)-1-((3aR,5S,6R,6aR)-6-benzyloxymethyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-2-methanesulfonyloxy-ethyl ester 
• 314061-35-3 2-((3aR,5R,6R,6aR)-6-Benzyloxymethyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-ethanol 
• 85315-74-8 3-C-(benzyloxymethyl)-3,5,6-trideoxy-1,2-O-isopropylidene-α-D-ribo-5-hexenofuranose 
• 377079-48-6 C₄₀H₄₂N₂O₁₁S₂ 
• 377079-33-9 Toluene-4-sulfonic acid (2S,3S,4R,5R)-2,3-bis-benzyloxymethyl-4-hydroxy-5-(5-methyl-2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-tetrahydro-furan-2-ylmethyl ester 
• 377079-45-3 Benzoic acid (R)-2-[(2S,3R,4R,5R)-4-acetoxy-3-benzyloxymethyl-5-(5-methyl-2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-tetrahydro-furan-2-yl]-2-benzyloxy-ethyl ester 
• 377079-34-0 Toluene-4-sulfonic acid (2S,3S,4R,5R)-2,3-bis-benzyloxymethyl-5-(2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-4-hydroxy-tetrahydro-furan-2-ylmethyl ester 
• 377079-29-3 Acetic acid (2S,3S,4R,5R)-4-acetoxy-2,3-bis-benzyloxymethyl-5-(5-methyl-2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-tetrahydro-furan-2-ylmethyl ester 
• 377079-30-6 Acetic acid (2S,3S,4R,5R)-4-acetoxy-2,3-bis-benzyloxymethyl-5-(2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-tetrahydro-furan-2-ylmethyl ester 
• 377079-31-7 1-((2R,3R,4S,5R)-4,5-Bis-benzyloxymethyl-3-hydroxy-5-hydroxymethyl-tetrahydro-furan-2-yl)-5-methyl-1H-pyrimidine-2,4-dione 
• 377079-43-1 Benzoic acid (R)-2-benzyloxy-2-((2S,3R,4R)-4,5-diacetoxy-3-benzyloxymethyl-tetrahydro-furan-2-yl)-ethyl ester 
• 377079-47-5 1-[(2R,3R,4S,5S)-5-((R)-1-Benzyloxy-2-hydroxy-ethyl)-4-benzyloxymethyl-3-hydroxy-tetrahydro-furan-2-yl]-5-methyl-1H-pyrimidine-2,4-dione 

Relevant articles and documents

Synthesis and biological evaluation of thymine nucleosides fused with 3′,4′-tetrahydrofuran ring

The pyrimidine nucleosides fused with 3′,4′-tetrahydrofuran ring were successfully synthesized, starting from 1,2; 5,6-di-O-isopropylidene-D-glucose and assayed for antiviral activities against HIV-1, HIV-2, EMCV, Cox. B3 and VSV. Thymine analogue (5) and

Synthesis of novel 3′-deoxy-3′-C-hydroxymethyl nucleosides with conformationally rigid sugar moiety as potential antiviral agents

Based on the fact that the ring expanded 3′-C-hydroxymethyl analogue of oxetanocin A exhibited potent antiviral activity, two types of conformationally rigid 3′-C-hydroxymethyl derivatives in which 2′-hydroxyl group is linked to the 4′-position or to the 6′-position were synthesized starting from 1,2;5,6-di-O-isopropylidene-D-glucose, respectively.

Chiral Synthesis of Polyketide-derived Natural Products. Part 5. Synthesis of a Chiral Segment Corresponding to the C-1-C-5 Unit of Erythromycin A from D-Glucose

As a right-hand segment with three consecutive chiral centres corresponding to the C-1-C-5 unit of erythromycin A (1), (2S,3R,4S)-3,5-isopropylidenedioxy-2,4-dimethylpentanal (32) was synthesized from D-glucose (5) by application of MPM (4-methoxybenzyl)