866771-99-5

Basic information

• Product Name: [(4'R,5'R)-5'-(benzyloxy)-2',2'-dimethyl-1',3'-dioxan-4'-yl]methanol
• Synonyms: [(4'R,5'R)-5'-(benzyloxy)-2',2'-dimethyl-1',3'-dioxan-4'-yl]methanol
• CAS NO: 866771-99-5
• Molecular Weight: 252.31
• Mol File: 866771-99-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [(4'R,5'R)-5'-(benzyloxy)-2',2'-dimethyl-1',3'-dioxan-4'-yl]methanol(CAS DataBase Reference)
• NIST Chemistry Reference: [(4'R,5'R)-5'-(benzyloxy)-2',2'-dimethyl-1',3'-dioxan-4'-yl]methanol(866771-99-5)
• EPA Substance Registry System: [(4'R,5'R)-5'-(benzyloxy)-2',2'-dimethyl-1',3'-dioxan-4'-yl]methanol(866771-99-5)

Safety Data

• Hazardous Substances Data: 866771-99-5(Hazardous Substances Data)

Upstream product

• 100906-45-4 (5S,6S)-6-(benzyloxy)-2,2-dimethyl-1,3-dioxepan-5-ol 
• 1611459-83-6 [(4'R,5'R)-5'-(benzyloxy)-2',2'-dimethyl-1',3'-dioxan-4'-yl]methyl benzoate 
• 1611459-80-3 (2R,3R)-3-(benzyloxy)-2,4-dihydroxybutyl benzoate 
• 1611459-79-0 5-O-benzoyl-3-O-benzyl-1,2-O-isopropylidene-α-D-xylofuranose 
• 34370-91-7 3-O-benzyl-1,2-O-isopropylidene-α-D-xylofuranose 
• 185541-37-1 1,2-O-isopropylidene-3-O-benzyl-5-O-triphenylmethyl-α-D-xylofuranoside 
• 1611459-82-5 C₁₈H₁₈O₅ 
• 100-52-7 benzaldehyde 
• 84379-51-1 2-O-benzyl-L-threitol 
• 38270-72-3 dimethyl 2,3-O-benzylidene-L-tartrate 
• 67-64-1 acetone 
• 77-76-9 2,2-dimethoxy-propane 

Downstream Products

• 84379-53-3 2-O-benzyl-3,4-O-isopropylidene-L-threitol 
• 100906-45-4 (5S,6S)-6-(benzyloxy)-2,2-dimethyl-1,3-dioxepan-5-ol 
• 1611460-11-7 (4R)-4-[(1'R,2'R)-2'-(benzyloxy)-1',3'-dihydroxypropyl]oxazolidin-2-one 
• 1611460-13-9 (4R)-4-[(1'R,2'R)-2'-(benzyloxy)-1'-hydroxy-3'-(trityloxy)propyl]oxazolidin-2-one 
• 1611460-15-1 (4R)-3-benzyl-4-[(1'R,2'R)-1',2'-bis(benzyloxy)-3'-(trityloxy)propyl]oxazolidin-2-one 
• 1611460-17-3 (4R)-3-benzyl-4-[(1'R,2'R)-1',2'-bis(benzyloxy)-3'-hydroxypropyl]oxazolidin-2-one 
• 1611460-18-4 (4S)-3-benzyl-4-[(1'R,2'R)-1',2'-bis(benzyloxy)-3'-hydroxypropyl]oxazolidin-2-one 
• 1611460-23-1 (4S)-3-benzyl-4-[(1'R,2'R,3'E)-1',2'-bis(benzyloxy)hexadec-3'-en-1'-yl]oxazolidin-2-one 
• 1611460-22-0 (4S)-3-benzyl-4-[(1'R,2'R,3'Z)-1',2'-bis(benzyloxy)hexadec-3'-en-1'-yl]oxazolidin-2-one 
• 1611459-85-8 ethyl (Z)-3-[(4'R,5'R)-5'-(benzyloxy)-2',2'-dimethyl-1',3'-dioxan-4'-yl]acrylate 
• 866772-34-1 C₁₄H₁₈O₄ 
• 1611459-87-0 (Z)-3-[(4'R,5'R)-5'-(benzyloxy)-2',2'-dimethyl-1',3'-dioxan-4'-yl]prop-2-en-1-ol 
• 1611459-89-2 C₁₇H₂₄O₆S 
• 1611459-95-0 C₁₈H₂₂Cl₃NO₄ 

Relevant articles and documents

Total synthesis of (-)-jaspine B and its 4-epi-analogue from d-xylose

The total synthesis of the HCl salts of (-)-jaspine B ent-1 and its 4-epi-congener ent-4 was accomplished starting from the common template 13 derived from d-xylose. The cornerstone of our synthesis was [3,3]- heterosigmatropic rearrangements, which effec